1 Ocak 2010 Dergi makalesi Açık Erişim

Guney, Emel; Yilmaz, Veysel T.; Sengul, Abdurrahman; Buyukgungor, Orhan

Citation Style Language JSON

{
  "DOI": "10.1016/j.ica.2009.11.018", 
  "abstract": "[Pd(sac)(terpy)](sac)center dot 4H(2)O (1), [Pt(sac)(terpy)](sac)center dot 5H(2)O (2), [PdCl(terpy)](sac)center dot 2H(2)O (3) and [PtCl(terpy)](sac)center dot 2H(2)O (4) (sac = saccharinate, and terpy = 2,2': 6',2 ''-terpyridine) have been synthesized and characterized by elemental analysis, FT-IR, H-1 NMR and C-13 NMR. In 1 and 2, a tridentate terpy ligand together with an N-coordinated sac ligand form the square-planar geometry around the palladium(II) or platinum(II) ions, while one sac anion remains outside the coordination sphere as a counter-ion. Xray single crystal studies show that the [M(sac)(terpy)](+) ions in 1 and 2 reside in the centers of a hydrogen bonded honeycomb network formed by the uncoordinated sac ions and the lattice water molecules. Complexes 3 and 4 are isostructural and consist of a [M(Cl)(terpy)](+) cation, a sac anion and two lattice water molecules. The [M(Cl)(terpy)](+) ions interact with each other via M-M and pi-pi stacking interactions and these p interacted units are assembled to a 2D network by water bridges involving the sac ions and lattice water molecules. Convenient synthetic paths for 1-4 are also presented, and spectral, luminescence and thermal properties were discussed. (C) 2009 Elsevier B. V. All rights reserved.", 
  "author": [
    {
      "family": "Guney", 
      "given": " Emel"
    }, 
    {
      "family": "Yilmaz", 
      "given": " Veysel T."
    }, 
    {
      "family": "Sengul", 
      "given": " Abdurrahman"
    }, 
    {
      "family": "Buyukgungor", 
      "given": " Orhan"
    }
  ], 
  "container_title": "INORGANICA CHIMICA ACTA", 
  "id": "25939", 
  "issue": "2", 
  "issued": {
    "date-parts": [
      [
        2010, 
        1, 
        1
      ]
    ]
  }, 
  "page": "438-448", 
  "title": "Platinum(II) and palladium(II) saccharinato complexes with 2,2 ':6 ',2 ''-terpyridine: Synthesis, characterization, crystal structures, photoluminescence and thermal studies", 
  "type": "article-journal", 
  "volume": "363"
}