1 Ocak 2010 Dergi makalesi Açık Erişim

Guney, Emel; Yilmaz, Veysel T.; Sengul, Abdurrahman; Buyukgungor, Orhan

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/25939</identifier>
  <creators>
    <creator>
      <creatorName>Guney, Emel</creatorName>
      <givenName>Emel</givenName>
      <familyName>Guney</familyName>
      <affiliation>Uludag Univ, Dept Chem, Fac Arts &amp; Sci, TR-16059 Bursa, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Yilmaz, Veysel T.</creatorName>
      <givenName>Veysel T.</givenName>
      <familyName>Yilmaz</familyName>
      <affiliation>Uludag Univ, Dept Chem, Fac Arts &amp; Sci, TR-16059 Bursa, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Sengul, Abdurrahman</creatorName>
      <givenName>Abdurrahman</givenName>
      <familyName>Sengul</familyName>
      <affiliation>Karaelmas Univ, Dept Chem, Fac Arts &amp; Sci, TR-67100 Zonguldak, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Buyukgungor, Orhan</creatorName>
      <givenName>Orhan</givenName>
      <familyName>Buyukgungor</familyName>
      <affiliation>Ondokuz Mayis Univ, Dept Phys, Fac Arts &amp; Sci, TR-55139 Samsun, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Platinum(Ii) And Palladium(Ii) Saccharinato Complexes With 2,2 ':6 ',2 ''-Terpyridine: Synthesis, Characterization, Crystal Structures, Photoluminescence And Thermal Studies</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2010</publicationYear>
  <dates>
    <date dateType="Issued">2010-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/25939</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.ica.2009.11.018</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">[Pd(sac)(terpy)](sac)center dot 4H(2)O (1), [Pt(sac)(terpy)](sac)center dot 5H(2)O (2), [PdCl(terpy)](sac)center dot 2H(2)O (3) and [PtCl(terpy)](sac)center dot 2H(2)O (4) (sac = saccharinate, and terpy = 2,2': 6',2 ''-terpyridine) have been synthesized and characterized by elemental analysis, FT-IR, H-1 NMR and C-13 NMR. In 1 and 2, a tridentate terpy ligand together with an N-coordinated sac ligand form the square-planar geometry around the palladium(II) or platinum(II) ions, while one sac anion remains outside the coordination sphere as a counter-ion. Xray single crystal studies show that the [M(sac)(terpy)](+) ions in 1 and 2 reside in the centers of a hydrogen bonded honeycomb network formed by the uncoordinated sac ions and the lattice water molecules. Complexes 3 and 4 are isostructural and consist of a [M(Cl)(terpy)](+) cation, a sac anion and two lattice water molecules. The [M(Cl)(terpy)](+) ions interact with each other via M-M and pi-pi stacking interactions and these p interacted units are assembled to a 2D network by water bridges involving the sac ions and lattice water molecules. Convenient synthetic paths for 1-4 are also presented, and spectral, luminescence and thermal properties were discussed. (C) 2009 Elsevier B. V. All rights reserved.</description>
  </descriptions>
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