1 Ocak 2021 Dergi makalesi Açık Erişim

Nawaz, Zahid; Gurbuz, Nevin; Zafar, Muhammad Naveed; Tahir, Muhammad Nawaz; Ashfaq, Muhammad; Karci, Huseyin; Ozdemir, Ismail

JSON-LD (schema.org)

{
  "@context": "https://schema.org/", 
  "@id": 238786, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "name": "Nawaz, Zahid"
    }, 
    {
      "@type": "Person", 
      "name": "Gurbuz, Nevin"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan", 
      "name": "Zafar, Muhammad Naveed"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Univ Sargodha, Dept Phys, Sargodha 40100, Pakistan", 
      "name": "Tahir, Muhammad Nawaz"
    }, 
    {
      "@type": "Person", 
      "name": "Ashfaq, Muhammad"
    }, 
    {
      "@type": "Person", 
      "name": "Karci, Huseyin"
    }, 
    {
      "@type": "Person", 
      "name": "Ozdemir, Ismail"
    }
  ], 
  "datePublished": "2021-01-01", 
  "description": "The growing interest of industry in the field of bi(hetero)arenes compounds, motivated us to synthesize these compounds via homogeneous catalytic route by using Pd PEPPSI-type complexes through direct arylation. In this work, the five new Pd PEPPSI-type complexes bearing NHC spectator ligands were synthesized and characterized by a bunch of spectroscopic techniques. Further confirmations of structural details were provided by a single crystal X-ray diffraction study of one pro-ligand and one complex. All these newly synthesized Pd-carbene complexes were found significantly active as catalysts toward direct arylation of five members heterocyclic compounds such as n-propylthaizole, 2-acetylfurane and 2-acetylthiophene with aryl bromides derivatives. These catalysts give significantly good results within two hours with just 1 mol % catalyst loading.", 
  "headline": "Direct arylation (hetero-coupling) of heteroarenes via unsymmetrical palladium-PEPPSI-NHC type complexes", 
  "identifier": 238786, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Direct arylation (hetero-coupling) of heteroarenes via unsymmetrical palladium-PEPPSI-NHC type complexes", 
  "url": "https://aperta.ulakbim.gov.tr/record/238786"
}