1 Ocak 2021 Dergi makalesi Açık Erişim

Nawaz, Zahid; Gurbuz, Nevin; Zafar, Muhammad Naveed; Tahir, Muhammad Nawaz; Ashfaq, Muhammad; Karci, Huseyin; Ozdemir, Ismail

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/238786</identifier>
  <creators>
    <creator>
      <creatorName>Nawaz, Zahid</creatorName>
      <givenName>Zahid</givenName>
      <familyName>Nawaz</familyName>
    </creator>
    <creator>
      <creatorName>Gurbuz, Nevin</creatorName>
      <givenName>Nevin</givenName>
      <familyName>Gurbuz</familyName>
    </creator>
    <creator>
      <creatorName>Zafar, Muhammad Naveed</creatorName>
      <givenName>Muhammad Naveed</givenName>
      <familyName>Zafar</familyName>
      <affiliation>Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan</affiliation>
    </creator>
    <creator>
      <creatorName>Tahir, Muhammad Nawaz</creatorName>
      <givenName>Muhammad Nawaz</givenName>
      <familyName>Tahir</familyName>
      <affiliation>Univ Sargodha, Dept Phys, Sargodha 40100, Pakistan</affiliation>
    </creator>
    <creator>
      <creatorName>Ashfaq, Muhammad</creatorName>
      <givenName>Muhammad</givenName>
      <familyName>Ashfaq</familyName>
    </creator>
    <creator>
      <creatorName>Karci, Huseyin</creatorName>
      <givenName>Huseyin</givenName>
      <familyName>Karci</familyName>
    </creator>
    <creator>
      <creatorName>Ozdemir, Ismail</creatorName>
      <givenName>Ismail</givenName>
      <familyName>Ozdemir</familyName>
    </creator>
  </creators>
  <titles>
    <title>Direct Arylation (Hetero-Coupling) Of Heteroarenes Via Unsymmetrical Palladium-Peppsi-Nhc Type Complexes</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2021</publicationYear>
  <dates>
    <date dateType="Issued">2021-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/238786</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.poly.2021.115412</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">The growing interest of industry in the field of bi(hetero)arenes compounds, motivated us to synthesize these compounds via homogeneous catalytic route by using Pd PEPPSI-type complexes through direct arylation. In this work, the five new Pd PEPPSI-type complexes bearing NHC spectator ligands were synthesized and characterized by a bunch of spectroscopic techniques. Further confirmations of structural details were provided by a single crystal X-ray diffraction study of one pro-ligand and one complex. All these newly synthesized Pd-carbene complexes were found significantly active as catalysts toward direct arylation of five members heterocyclic compounds such as n-propylthaizole, 2-acetylfurane and 2-acetylthiophene with aryl bromides derivatives. These catalysts give significantly good results within two hours with just 1 mol % catalyst loading.</description>
  </descriptions>
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