1 Ocak 2021 Dergi makalesi Açık Erişim

Nawaz, Zahid; Gurbuz, Nevin; Zafar, Muhammad Naveed; Tahir, Muhammad Nawaz; Ashfaq, Muhammad; Karci, Huseyin; Ozdemir, Ismail

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{
  "DOI": "10.1016/j.poly.2021.115412", 
  "abstract": "The growing interest of industry in the field of bi(hetero)arenes compounds, motivated us to synthesize these compounds via homogeneous catalytic route by using Pd PEPPSI-type complexes through direct arylation. In this work, the five new Pd PEPPSI-type complexes bearing NHC spectator ligands were synthesized and characterized by a bunch of spectroscopic techniques. Further confirmations of structural details were provided by a single crystal X-ray diffraction study of one pro-ligand and one complex. All these newly synthesized Pd-carbene complexes were found significantly active as catalysts toward direct arylation of five members heterocyclic compounds such as n-propylthaizole, 2-acetylfurane and 2-acetylthiophene with aryl bromides derivatives. These catalysts give significantly good results within two hours with just 1 mol % catalyst loading.", 
  "author": [
    {
      "family": "Nawaz", 
      "given": " Zahid"
    }, 
    {
      "family": "Gurbuz", 
      "given": " Nevin"
    }, 
    {
      "family": "Zafar", 
      "given": " Muhammad Naveed"
    }, 
    {
      "family": "Tahir", 
      "given": " Muhammad Nawaz"
    }, 
    {
      "family": "Ashfaq", 
      "given": " Muhammad"
    }, 
    {
      "family": "Karci", 
      "given": " Huseyin"
    }, 
    {
      "family": "Ozdemir", 
      "given": " Ismail"
    }
  ], 
  "container_title": "POLYHEDRON", 
  "id": "238786", 
  "issued": {
    "date-parts": [
      [
        2021, 
        1, 
        1
      ]
    ]
  }, 
  "title": "Direct arylation (hetero-coupling) of heteroarenes via unsymmetrical palladium-PEPPSI-NHC type complexes", 
  "type": "article-journal", 
  "volume": "208"
}