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Aromatisation in adducts of alpha-terpinene: Influence of hindered internal rotations

Kaya, Afsin Ahmet; Sengul, Mehmet Emin; Menzek, Abdullah; Kayaardi, Ibrahim; Karakus, Murat; Sahin, Ertan


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<oai_dc:dc xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd">
  <dc:creator>Kaya, Afsin Ahmet</dc:creator>
  <dc:creator>Sengul, Mehmet Emin</dc:creator>
  <dc:creator>Menzek, Abdullah</dc:creator>
  <dc:creator>Kayaardi, Ibrahim</dc:creator>
  <dc:creator>Karakus, Murat</dc:creator>
  <dc:creator>Sahin, Ertan</dc:creator>
  <dc:date>2011-01-01</dc:date>
  <dc:description>Each adduct of alpha-terpinene with p-quinone and 1,4-naphthoquinone in Ac(2)O/Et(3)N at 180 C gives two aromatic products, one of which had a distinctive smell formed by the loss of an ethylene group. Here, we report the crystal structure of (1RS, 4RS)-1-isopropyl-4-methyl-1,4-dihydro-1,4-ethanoanthracene-9,10-diyl diacetate. It is crystallised in an orthorhombic space group, Pbca, with cell dimensions a = 10.2899(7), b = 19.7804(9), c = 19.7519(8) angstrom and Z = 8. According to its NMR and X-ray diffraction data, the isopropyl and acetate groups slowly rotate.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/21371</dc:identifier>
  <dc:identifier>oai:zenodo.org:21371</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>JOURNAL OF CHEMICAL RESEARCH 9 540-544</dc:source>
  <dc:title>Aromatisation in adducts of alpha-terpinene: Influence of hindered internal rotations</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
</oai_dc:dc>
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