1 Ocak 2011 Dergi makalesi Açık Erişim

Kaya, Afsin Ahmet; Sengul, Mehmet Emin; Menzek, Abdullah; Kayaardi, Ibrahim; Karakus, Murat; Sahin, Ertan

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  "@id": 21371, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "name": "Kaya, Afsin Ahmet"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Ataturk Univ, Dept Chem, Fac Sci, TR-25240 Erzurum, Turkey", 
      "name": "Sengul, Mehmet Emin"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Ataturk Univ, Dept Chem, Fac Sci, TR-25240 Erzurum, Turkey", 
      "name": "Menzek, Abdullah"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Ataturk Univ, Dept Chem, Fac Sci, TR-25240 Erzurum, Turkey", 
      "name": "Kayaardi, Ibrahim"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Ataturk Univ, Dept Chem, Fac Sci, TR-25240 Erzurum, Turkey", 
      "name": "Karakus, Murat"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Ataturk Univ, Dept Chem, Fac Sci, TR-25240 Erzurum, Turkey", 
      "name": "Sahin, Ertan"
    }
  ], 
  "datePublished": "2011-01-01", 
  "description": "Each adduct of alpha-terpinene with p-quinone and 1,4-naphthoquinone in Ac(2)O/Et(3)N at 180 C gives two aromatic products, one of which had a distinctive smell formed by the loss of an ethylene group. Here, we report the crystal structure of (1RS, 4RS)-1-isopropyl-4-methyl-1,4-dihydro-1,4-ethanoanthracene-9,10-diyl diacetate. It is crystallised in an orthorhombic space group, Pbca, with cell dimensions a = 10.2899(7), b = 19.7804(9), c = 19.7519(8) angstrom and Z = 8. According to its NMR and X-ray diffraction data, the isopropyl and acetate groups slowly rotate.", 
  "headline": "Aromatisation in adducts of alpha-terpinene: Influence of hindered internal rotations", 
  "identifier": 21371, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Aromatisation in adducts of alpha-terpinene: Influence of hindered internal rotations", 
  "url": "https://aperta.ulakbim.gov.tr/record/21371"
}