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Aromatisation in adducts of alpha-terpinene: Influence of hindered internal rotations

Kaya, Afsin Ahmet; Sengul, Mehmet Emin; Menzek, Abdullah; Kayaardi, Ibrahim; Karakus, Murat; Sahin, Ertan


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{
  "DOI": "10.3184/174751911X13155890649111", 
  "abstract": "Each adduct of alpha-terpinene with p-quinone and 1,4-naphthoquinone in Ac(2)O/Et(3)N at 180 C gives two aromatic products, one of which had a distinctive smell formed by the loss of an ethylene group. Here, we report the crystal structure of (1RS, 4RS)-1-isopropyl-4-methyl-1,4-dihydro-1,4-ethanoanthracene-9,10-diyl diacetate. It is crystallised in an orthorhombic space group, Pbca, with cell dimensions a = 10.2899(7), b = 19.7804(9), c = 19.7519(8) angstrom and Z = 8. According to its NMR and X-ray diffraction data, the isopropyl and acetate groups slowly rotate.", 
  "author": [
    {
      "family": "Kaya", 
      "given": " Afsin Ahmet"
    }, 
    {
      "family": "Sengul", 
      "given": " Mehmet Emin"
    }, 
    {
      "family": "Menzek", 
      "given": " Abdullah"
    }, 
    {
      "family": "Kayaardi", 
      "given": " Ibrahim"
    }, 
    {
      "family": "Karakus", 
      "given": " Murat"
    }, 
    {
      "family": "Sahin", 
      "given": " Ertan"
    }
  ], 
  "container_title": "JOURNAL OF CHEMICAL RESEARCH", 
  "id": "21371", 
  "issue": "9", 
  "issued": {
    "date-parts": [
      [
        2011, 
        1, 
        1
      ]
    ]
  }, 
  "page": "540-544", 
  "title": "Aromatisation in adducts of alpha-terpinene: Influence of hindered internal rotations", 
  "type": "article-journal"
}
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