Dergi makalesi Açık Erişim
Kaya, Afsin Ahmet; Sengul, Mehmet Emin; Menzek, Abdullah; Kayaardi, Ibrahim; Karakus, Murat; Sahin, Ertan
{ "DOI": "10.3184/174751911X13155890649111", "abstract": "Each adduct of alpha-terpinene with p-quinone and 1,4-naphthoquinone in Ac(2)O/Et(3)N at 180 C gives two aromatic products, one of which had a distinctive smell formed by the loss of an ethylene group. Here, we report the crystal structure of (1RS, 4RS)-1-isopropyl-4-methyl-1,4-dihydro-1,4-ethanoanthracene-9,10-diyl diacetate. It is crystallised in an orthorhombic space group, Pbca, with cell dimensions a = 10.2899(7), b = 19.7804(9), c = 19.7519(8) angstrom and Z = 8. According to its NMR and X-ray diffraction data, the isopropyl and acetate groups slowly rotate.", "author": [ { "family": "Kaya", "given": " Afsin Ahmet" }, { "family": "Sengul", "given": " Mehmet Emin" }, { "family": "Menzek", "given": " Abdullah" }, { "family": "Kayaardi", "given": " Ibrahim" }, { "family": "Karakus", "given": " Murat" }, { "family": "Sahin", "given": " Ertan" } ], "container_title": "JOURNAL OF CHEMICAL RESEARCH", "id": "21371", "issue": "9", "issued": { "date-parts": [ [ 2011, 1, 1 ] ] }, "page": "540-544", "title": "Aromatisation in adducts of alpha-terpinene: Influence of hindered internal rotations", "type": "article-journal" }
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