1 Ocak 2011 Dergi makalesi Açık Erişim

Kabay, Nilgun; Karadeniz, Hulya; Demirayak, Nuray; Gok, Yasar

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/18843</identifier>
  <creators>
    <creator>
      <creatorName>Kabay, Nilgun</creatorName>
      <givenName>Nilgun</givenName>
      <familyName>Kabay</familyName>
      <affiliation>Pamukkale Univ, Dept Chem, TR-20017 Denizli, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Karadeniz, Hulya</creatorName>
      <givenName>Hulya</givenName>
      <familyName>Karadeniz</familyName>
      <affiliation>Council Forens Med, TR-61080 Trabzon, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Demirayak, Nuray</creatorName>
      <givenName>Nuray</givenName>
      <familyName>Demirayak</familyName>
      <affiliation>Pamukkale Univ, Dept Chem, TR-20017 Denizli, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Gok, Yasar</creatorName>
      <givenName>Yasar</givenName>
      <familyName>Gok</familyName>
      <affiliation>Pamukkale Univ, Dept Chem, TR-20017 Denizli, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Synthesis And Characterization Of New Metallo And Metal-Free Porphyrazines Containing Dioxadithia (O2S2) And Tetrathia (S-4) Macrocyclic Moieties</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2011</publicationYear>
  <dates>
    <date dateType="Issued">2011-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/18843</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.inoche.2011.01.039</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">The synthesis of new magnesium porphyrazines, peripherally substituted with 14-membered dioxa-dithia (O2S2) and tetrathia (S-4) macrocycles has been accomplished by cyclotetramerization of (6Z)-1,3,4,9,10,12-hexahydro-2,5,8,11-benzodioxadithia-cyclotetradecine-6,7-dicarbonitrile (3) or (62)-1,3,4,9,10,12-hexahydro-2,5,8,11-benzotetrathiacyclotetradecine-6,7-dicarbonitrile (5) in the presence of magnesium butanolate. The precursors were prepared from disodium salt of dithiomaleonitrile and o-xylenebis(1-chloro-3-oxapentane) (2) or o-xylenebis(1-chloro-3-thiapentane) (4). The metal-free porphyrazines are obtained by the treatment of these magnesium porphyrazines with trifluoroacetic acid. These new compounds are characterized by a combination of elemental analysis and H-1, C-13 NMR, IR, UV-vis and MS spectral data. Crown Copyright (C) 2011 Published by Elsevier B.V. All rights reserved.</description>
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