1 Ocak 2011 Dergi makalesi Açık Erişim

Kabay, Nilgun; Karadeniz, Hulya; Demirayak, Nuray; Gok, Yasar

Citation Style Language JSON

{
  "DOI": "10.1016/j.inoche.2011.01.039", 
  "abstract": "The synthesis of new magnesium porphyrazines, peripherally substituted with 14-membered dioxa-dithia (O2S2) and tetrathia (S-4) macrocycles has been accomplished by cyclotetramerization of (6Z)-1,3,4,9,10,12-hexahydro-2,5,8,11-benzodioxadithia-cyclotetradecine-6,7-dicarbonitrile (3) or (62)-1,3,4,9,10,12-hexahydro-2,5,8,11-benzotetrathiacyclotetradecine-6,7-dicarbonitrile (5) in the presence of magnesium butanolate. The precursors were prepared from disodium salt of dithiomaleonitrile and o-xylenebis(1-chloro-3-oxapentane) (2) or o-xylenebis(1-chloro-3-thiapentane) (4). The metal-free porphyrazines are obtained by the treatment of these magnesium porphyrazines with trifluoroacetic acid. These new compounds are characterized by a combination of elemental analysis and H-1, C-13 NMR, IR, UV-vis and MS spectral data. Crown Copyright (C) 2011 Published by Elsevier B.V. All rights reserved.", 
  "author": [
    {
      "family": "Kabay", 
      "given": " Nilgun"
    }, 
    {
      "family": "Karadeniz", 
      "given": " Hulya"
    }, 
    {
      "family": "Demirayak", 
      "given": " Nuray"
    }, 
    {
      "family": "Gok", 
      "given": " Yasar"
    }
  ], 
  "container_title": "INORGANIC CHEMISTRY COMMUNICATIONS", 
  "id": "18843", 
  "issue": "5", 
  "issued": {
    "date-parts": [
      [
        2011, 
        1, 
        1
      ]
    ]
  }, 
  "page": "641-644", 
  "title": "Synthesis and characterization of new metallo and metal-free porphyrazines containing dioxadithia (O2S2) and tetrathia (S-4) macrocyclic moieties", 
  "type": "article-journal", 
  "volume": "14"
}