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Dendronized Polystyrene via Orthogonal Double-Click Reactions

Tonga, Murat; Tonga, Gulen Yesilbag; Seber, Gonca; Gok, Ozgul; Sanyal, Amitav


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  <dc:creator>Tonga, Murat</dc:creator>
  <dc:creator>Tonga, Gulen Yesilbag</dc:creator>
  <dc:creator>Seber, Gonca</dc:creator>
  <dc:creator>Gok, Ozgul</dc:creator>
  <dc:creator>Sanyal, Amitav</dc:creator>
  <dc:date>2013-01-01</dc:date>
  <dc:description>Dendronized copolymers bearing two different dendrons as side chains have been synthesized using a modular orthogonal double-click reaction based strategy. The orthogonality of the Huisgen-type azide-alkyne cycloaddition and the Diels-Alder reaction was utilized to attach different dendrons to the polymer backbone via the graft-to strategy. First through third generations of polyaryl ether dendrons appended with an alkyne group and polyester dendrons possessing a furan-protected maleimide group at their focal point were reacted with a styrene based copolymer containing azide and anthracene moieties as side chains. The efficiency and selectivity of the orthogonal dendronization of the copolymers were examined via various analytical methods such as H-1 NMR spectroscopy, FTIR and gel permeation chromatography. (c) 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 5029-5037</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/15135</dc:identifier>
  <dc:identifier>oai:zenodo.org:15135</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 51(23) 5029-5037</dc:source>
  <dc:title>Dendronized Polystyrene via Orthogonal Double-Click Reactions</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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