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Dendronized Polystyrene via Orthogonal Double-Click Reactions

Tonga, Murat; Tonga, Gulen Yesilbag; Seber, Gonca; Gok, Ozgul; Sanyal, Amitav


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{
  "DOI": "10.1002/pola.26933", 
  "abstract": "Dendronized copolymers bearing two different dendrons as side chains have been synthesized using a modular orthogonal double-click reaction based strategy. The orthogonality of the Huisgen-type azide-alkyne cycloaddition and the Diels-Alder reaction was utilized to attach different dendrons to the polymer backbone via the graft-to strategy. First through third generations of polyaryl ether dendrons appended with an alkyne group and polyester dendrons possessing a furan-protected maleimide group at their focal point were reacted with a styrene based copolymer containing azide and anthracene moieties as side chains. The efficiency and selectivity of the orthogonal dendronization of the copolymers were examined via various analytical methods such as H-1 NMR spectroscopy, FTIR and gel permeation chromatography. (c) 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 5029-5037", 
  "author": [
    {
      "family": "Tonga", 
      "given": " Murat"
    }, 
    {
      "family": "Tonga", 
      "given": " Gulen Yesilbag"
    }, 
    {
      "family": "Seber", 
      "given": " Gonca"
    }, 
    {
      "family": "Gok", 
      "given": " Ozgul"
    }, 
    {
      "family": "Sanyal", 
      "given": " Amitav"
    }
  ], 
  "container_title": "JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY", 
  "id": "15135", 
  "issue": "23", 
  "issued": {
    "date-parts": [
      [
        2013, 
        1, 
        1
      ]
    ]
  }, 
  "page": "5029-5037", 
  "title": "Dendronized Polystyrene via Orthogonal Double-Click Reactions", 
  "type": "article-journal", 
  "volume": "51"
}
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