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Dendronized Polystyrene via Orthogonal Double-Click Reactions

Tonga, Murat; Tonga, Gulen Yesilbag; Seber, Gonca; Gok, Ozgul; Sanyal, Amitav


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/15135</identifier>
  <creators>
    <creator>
      <creatorName>Tonga, Murat</creatorName>
      <givenName>Murat</givenName>
      <familyName>Tonga</familyName>
      <affiliation>Bogazici Univ, Dept Chem, TR-34342 Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Tonga, Gulen Yesilbag</creatorName>
      <givenName>Gulen Yesilbag</givenName>
      <familyName>Tonga</familyName>
      <affiliation>Bogazici Univ, Dept Chem, TR-34342 Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Seber, Gonca</creatorName>
      <givenName>Gonca</givenName>
      <familyName>Seber</familyName>
      <affiliation>Bogazici Univ, Dept Chem, TR-34342 Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Gok, Ozgul</creatorName>
      <givenName>Ozgul</givenName>
      <familyName>Gok</familyName>
      <affiliation>Bogazici Univ, Dept Chem, TR-34342 Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Sanyal, Amitav</creatorName>
      <givenName>Amitav</givenName>
      <familyName>Sanyal</familyName>
      <affiliation>Bogazici Univ, Dept Chem, TR-34342 Istanbul, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Dendronized Polystyrene Via Orthogonal Double-Click Reactions</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2013</publicationYear>
  <dates>
    <date dateType="Issued">2013-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/15135</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1002/pola.26933</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">Dendronized copolymers bearing two different dendrons as side chains have been synthesized using a modular orthogonal double-click reaction based strategy. The orthogonality of the Huisgen-type azide-alkyne cycloaddition and the Diels-Alder reaction was utilized to attach different dendrons to the polymer backbone via the graft-to strategy. First through third generations of polyaryl ether dendrons appended with an alkyne group and polyester dendrons possessing a furan-protected maleimide group at their focal point were reacted with a styrene based copolymer containing azide and anthracene moieties as side chains. The efficiency and selectivity of the orthogonal dendronization of the copolymers were examined via various analytical methods such as H-1 NMR spectroscopy, FTIR and gel permeation chromatography. (c) 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 5029-5037</description>
  </descriptions>
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