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Preparation and photochromic properties of 2,3-bisarylbenz[f]indenones

Kose, Mahmut; Orhan, Ersin; Suzuki, Kazushi; Tutar, Ahmet; Unlu, Cihansel Sancak; Yokoyama, Yasushi


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  "@context": "https://schema.org/", 
  "@id": 14199, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Bulent Ecevit Univ, Fac Arts & Sci, Dept Chem, TR-67100 Zonguldak, Turkey", 
      "name": "Kose, Mahmut"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Duzce Univ, Fac Arts & Sci, Dept Chem, TR-81620 Duzce, Turkey", 
      "name": "Orhan, Ersin"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Yokohama Natl Univ, Grad Sch Engn, Dept Adv Mat Chem, Yokohama, Kanagawa 2408501, Japan", 
      "name": "Suzuki, Kazushi"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Sakarya Univ, Fac Arts & Sci, Dept Chem, TR-54187 Sakarya, Turkey", 
      "name": "Tutar, Ahmet"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Sakarya Univ, Fac Arts & Sci, Dept Chem, TR-54187 Sakarya, Turkey", 
      "name": "Unlu, Cihansel Sancak"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Yokohama Natl Univ, Grad Sch Engn, Dept Adv Mat Chem, Yokohama, Kanagawa 2408501, Japan", 
      "name": "Yokoyama, Yasushi"
    }
  ], 
  "datePublished": "2013-01-01", 
  "description": "From 2,3-dibromobenz[f]indenone, four compound: 2,3-bis(5-methyl-2-phenyl-4-thiazolyl)benz [f]indenone 10, 2,3-bis(3,5-dimethyl-4-isoxazolyl)benz[f]indenone 20, 3-(3,5-dimethyl-4-isoxazolyl)-2-(5-methyl-2-phenyl-4-thiazolyl)benz[f]indenone 30 and 2,3-bis(5-methyl-2-phenyl-4-thiazolyl)benz[f]indenol 40 were prepared, and their photochromic properties were investigated. Among them, photochrome 10 (weak photochromic) and its bisthiazolylbenz[f]indenol derivative 40 displayed photochromism. During ring closure photoreaction, photochrome 40 showed high conversion ratio (98.4%) with low diastereomeric excess (38%). (C) 2013 Elsevier B.V. All rights reserved.", 
  "headline": "Preparation and photochromic properties of 2,3-bisarylbenz[f]indenones", 
  "identifier": 14199, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Preparation and photochromic properties of 2,3-bisarylbenz[f]indenones", 
  "url": "https://aperta.ulakbim.gov.tr/record/14199"
}
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