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Preparation and photochromic properties of 2,3-bisarylbenz[f]indenones

Kose, Mahmut; Orhan, Ersin; Suzuki, Kazushi; Tutar, Ahmet; Unlu, Cihansel Sancak; Yokoyama, Yasushi


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        "affiliation": "Bulent Ecevit Univ, Fac Arts & Sci, Dept Chem, TR-67100 Zonguldak, Turkey", 
        "name": "Kose, Mahmut"
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      {
        "affiliation": "Duzce Univ, Fac Arts & Sci, Dept Chem, TR-81620 Duzce, Turkey", 
        "name": "Orhan, Ersin"
      }, 
      {
        "affiliation": "Yokohama Natl Univ, Grad Sch Engn, Dept Adv Mat Chem, Yokohama, Kanagawa 2408501, Japan", 
        "name": "Suzuki, Kazushi"
      }, 
      {
        "affiliation": "Sakarya Univ, Fac Arts & Sci, Dept Chem, TR-54187 Sakarya, Turkey", 
        "name": "Tutar, Ahmet"
      }, 
      {
        "affiliation": "Sakarya Univ, Fac Arts & Sci, Dept Chem, TR-54187 Sakarya, Turkey", 
        "name": "Unlu, Cihansel Sancak"
      }, 
      {
        "affiliation": "Yokohama Natl Univ, Grad Sch Engn, Dept Adv Mat Chem, Yokohama, Kanagawa 2408501, Japan", 
        "name": "Yokoyama, Yasushi"
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    ], 
    "description": "From 2,3-dibromobenz[f]indenone, four compound: 2,3-bis(5-methyl-2-phenyl-4-thiazolyl)benz [f]indenone 10, 2,3-bis(3,5-dimethyl-4-isoxazolyl)benz[f]indenone 20, 3-(3,5-dimethyl-4-isoxazolyl)-2-(5-methyl-2-phenyl-4-thiazolyl)benz[f]indenone 30 and 2,3-bis(5-methyl-2-phenyl-4-thiazolyl)benz[f]indenol 40 were prepared, and their photochromic properties were investigated. Among them, photochrome 10 (weak photochromic) and its bisthiazolylbenz[f]indenol derivative 40 displayed photochromism. During ring closure photoreaction, photochrome 40 showed high conversion ratio (98.4%) with low diastereomeric excess (38%). (C) 2013 Elsevier B.V. All rights reserved.", 
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      "pages": "50-53", 
      "title": "JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY", 
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    "publication_date": "2013-01-01", 
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    "title": "Preparation and photochromic properties of 2,3-bisarylbenz[f]indenones"
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