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Preparation and photochromic properties of 2,3-bisarylbenz[f]indenones

Kose, Mahmut; Orhan, Ersin; Suzuki, Kazushi; Tutar, Ahmet; Unlu, Cihansel Sancak; Yokoyama, Yasushi


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{
  "DOI": "10.1016/j.jphotochem.2013.01.012", 
  "abstract": "From 2,3-dibromobenz[f]indenone, four compound: 2,3-bis(5-methyl-2-phenyl-4-thiazolyl)benz [f]indenone 10, 2,3-bis(3,5-dimethyl-4-isoxazolyl)benz[f]indenone 20, 3-(3,5-dimethyl-4-isoxazolyl)-2-(5-methyl-2-phenyl-4-thiazolyl)benz[f]indenone 30 and 2,3-bis(5-methyl-2-phenyl-4-thiazolyl)benz[f]indenol 40 were prepared, and their photochromic properties were investigated. Among them, photochrome 10 (weak photochromic) and its bisthiazolylbenz[f]indenol derivative 40 displayed photochromism. During ring closure photoreaction, photochrome 40 showed high conversion ratio (98.4%) with low diastereomeric excess (38%). (C) 2013 Elsevier B.V. All rights reserved.", 
  "author": [
    {
      "family": "Kose", 
      "given": " Mahmut"
    }, 
    {
      "family": "Orhan", 
      "given": " Ersin"
    }, 
    {
      "family": "Suzuki", 
      "given": " Kazushi"
    }, 
    {
      "family": "Tutar", 
      "given": " Ahmet"
    }, 
    {
      "family": "Unlu", 
      "given": " Cihansel Sancak"
    }, 
    {
      "family": "Yokoyama", 
      "given": " Yasushi"
    }
  ], 
  "container_title": "JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY", 
  "id": "14199", 
  "issued": {
    "date-parts": [
      [
        2013, 
        1, 
        1
      ]
    ]
  }, 
  "page": "50-53", 
  "title": "Preparation and photochromic properties of 2,3-bisarylbenz[f]indenones", 
  "type": "article-journal", 
  "volume": "257"
}
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