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Synthesis and characterization of new soluble phthalocyanines substituted with four tetrathiamacrocycles through oxy bridges and their complexes with silver(I) and palladium(II) ions

Dabak, S; Gurek, AG; Musluoglu, E; Ahsen, V


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/96329</identifier>
  <creators>
    <creator>
      <creatorName>Dabak, S</creatorName>
      <givenName>S</givenName>
      <familyName>Dabak</familyName>
    </creator>
    <creator>
      <creatorName>Gurek, AG</creatorName>
      <givenName>AG</givenName>
      <familyName>Gurek</familyName>
    </creator>
    <creator>
      <creatorName>Musluoglu, E</creatorName>
      <givenName>E</givenName>
      <familyName>Musluoglu</familyName>
    </creator>
    <creator>
      <creatorName>Ahsen, V</creatorName>
      <givenName>V</givenName>
      <familyName>Ahsen</familyName>
    </creator>
  </creators>
  <titles>
    <title>Synthesis And Characterization Of New Soluble Phthalocyanines Substituted With Four Tetrathiamacrocycles Through Oxy Bridges And Their Complexes With Silver(I) And Palladium(Ii) Ions</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2001</publicationYear>
  <dates>
    <date dateType="Issued">2001-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/96329</alternateIdentifier>
  </alternateIdentifiers>
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    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsVersionOf">10.81043/aperta.96328</relatedIdentifier>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.81043/aperta.96329</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">The synthesis of a metal-free phthalocyanine (3) and metal phthalocyanines [4-7; M = Ni(II), Co(II), Cu(II) and Zn(II)] with four tetrathiamacrocycles obtained from 4-({3,6,10,13-tetrathiacyclotetradecyl}oxy)phthalonitrile (2) in the presence of dimethylaminoethanol or the corresponding anhydrous metal salts is described. The new soluble compounds have been characterized by elemental analysis, IR, H-1 and C-13 NMR, MS and UV-Visible spectra. The thermal stabilities have been determined by thermogravimetric analyses. Complexation of the tetrathiamacrocycles of 4 with silver(I) or palladium(II) yields forms pentanuclear compounds.</description>
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