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3-Hydroxychromone dyes exhibiting excited-state intramolecular proton transfer in water with efficient two-band fluorescence

Klymchenko, AS; Demchenko, AP


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/95217</identifier>
  <creators>
    <creator>
      <creatorName>Klymchenko, AS</creatorName>
      <givenName>AS</givenName>
      <familyName>Klymchenko</familyName>
    </creator>
    <creator>
      <creatorName>Demchenko, AP</creatorName>
      <givenName>AP</givenName>
      <familyName>Demchenko</familyName>
    </creator>
  </creators>
  <titles>
    <title>3-Hydroxychromone Dyes Exhibiting Excited-State Intramolecular Proton Transfer In Water With Efficient Two-Band Fluorescence</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2004</publicationYear>
  <dates>
    <date dateType="Issued">2004-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/95217</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1039/b316149h</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">We demonstrate that newly synthesised 7-acetamido-3-hydroxychromones, as well as their parent 3-hydroxychromone (3HC) analogues, exhibit excited-state intramolecular proton transfer reaction in polar protic media including water, resulting in well-resolved two-band fluorescence. Among all 3HCs reported so far, the new compounds show the highest quantum yields ever reported in water (4-13%), while maintaining the sensitive ratiometric response to solvent polarity. This makes them very promising precursors for the development of two-band fluorescent labels and probes, operating in water and other protic media.</description>
  </descriptions>
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