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3-Hydroxychromone dyes exhibiting excited-state intramolecular proton transfer in water with efficient two-band fluorescence

Klymchenko, AS; Demchenko, AP


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{
  "DOI": "10.1039/b316149h", 
  "abstract": "We demonstrate that newly synthesised 7-acetamido-3-hydroxychromones, as well as their parent 3-hydroxychromone (3HC) analogues, exhibit excited-state intramolecular proton transfer reaction in polar protic media including water, resulting in well-resolved two-band fluorescence. Among all 3HCs reported so far, the new compounds show the highest quantum yields ever reported in water (4-13%), while maintaining the sensitive ratiometric response to solvent polarity. This makes them very promising precursors for the development of two-band fluorescent labels and probes, operating in water and other protic media.", 
  "author": [
    {
      "family": "Klymchenko", 
      "given": " AS"
    }, 
    {
      "family": "Demchenko", 
      "given": " AP"
    }
  ], 
  "container_title": "NEW JOURNAL OF CHEMISTRY", 
  "id": "95217", 
  "issue": "6", 
  "issued": {
    "date-parts": [
      [
        2004, 
        1, 
        1
      ]
    ]
  }, 
  "page": "687-692", 
  "title": "3-Hydroxychromone dyes exhibiting excited-state intramolecular proton transfer in water with efficient two-band fluorescence", 
  "type": "article-journal", 
  "volume": "28"
}
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