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Mitani, T; Naitou, T; Matsuishi, K; Onari, S; Allakhverdiev, K; Gashimzade, F; Kerimova, T
<?xml version='1.0' encoding='utf-8'?> <resource xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://datacite.org/schema/kernel-4" xsi:schemaLocation="http://datacite.org/schema/kernel-4 http://schema.datacite.org/meta/kernel-4.1/metadata.xsd"> <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/95153</identifier> <creators> <creator> <creatorName>Mitani, T</creatorName> <givenName>T</givenName> <familyName>Mitani</familyName> </creator> <creator> <creatorName>Naitou, T</creatorName> <givenName>T</givenName> <familyName>Naitou</familyName> </creator> <creator> <creatorName>Matsuishi, K</creatorName> <givenName>K</givenName> <familyName>Matsuishi</familyName> </creator> <creator> <creatorName>Onari, S</creatorName> <givenName>S</givenName> <familyName>Onari</familyName> </creator> <creator> <creatorName>Allakhverdiev, K</creatorName> <givenName>K</givenName> <familyName>Allakhverdiev</familyName> </creator> <creator> <creatorName>Gashimzade, F</creatorName> <givenName>F</givenName> <familyName>Gashimzade</familyName> </creator> <creator> <creatorName>Kerimova, T</creatorName> <givenName>T</givenName> <familyName>Kerimova</familyName> </creator> </creators> <titles> <title>Raman Scattering In Cdga2Se4 Under Pressure</title> </titles> <publisher>Aperta</publisher> <publicationYear>2003</publicationYear> <dates> <date dateType="Issued">2003-01-01</date> </dates> <resourceType resourceTypeGeneral="Text">Journal article</resourceType> <alternateIdentifiers> <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/95153</alternateIdentifier> </alternateIdentifiers> <relatedIdentifiers> <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1002/pssb.200301579</relatedIdentifier> </relatedIdentifiers> <rightsList> <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights> <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights> </rightsList> <descriptions> <description descriptionType="Abstract">The Raman scattering spectra of CdGa2Se4 under pressure were investigated at 300 K up to 20.9 GPa. TO as well as LO modes were observed. Two stages were observed in the pressure dependences of Raman bands. Such a behaviour was attributed to the order-disorder phase transition in the cation sublattice. A first-order phase transition under pressure was observed at 20.2 GPa. Using the Harrison-Keating model of the lattice dynamics modified for crystals with the tetragonal structure, the bulk modulus B and the mode-Gruneisen parameters Gamma(i) were determined for the first time. It is shown that a better agreement between the experimental and calculated values of Gamma(i) is observed if one takes into consideration the different behaviour with pressure for the bond-bending and the bond-stretching parameters, which determine the low-(lower than 140 cm(-1)) and high-(higher than 140 cm(-1)) frequency phonons, respectively.</description> </descriptions> </resource>
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