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Raman scattering in CdGa2Se4 under pressure

Mitani, T; Naitou, T; Matsuishi, K; Onari, S; Allakhverdiev, K; Gashimzade, F; Kerimova, T


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/95153</identifier>
  <creators>
    <creator>
      <creatorName>Mitani, T</creatorName>
      <givenName>T</givenName>
      <familyName>Mitani</familyName>
    </creator>
    <creator>
      <creatorName>Naitou, T</creatorName>
      <givenName>T</givenName>
      <familyName>Naitou</familyName>
    </creator>
    <creator>
      <creatorName>Matsuishi, K</creatorName>
      <givenName>K</givenName>
      <familyName>Matsuishi</familyName>
    </creator>
    <creator>
      <creatorName>Onari, S</creatorName>
      <givenName>S</givenName>
      <familyName>Onari</familyName>
    </creator>
    <creator>
      <creatorName>Allakhverdiev, K</creatorName>
      <givenName>K</givenName>
      <familyName>Allakhverdiev</familyName>
    </creator>
    <creator>
      <creatorName>Gashimzade, F</creatorName>
      <givenName>F</givenName>
      <familyName>Gashimzade</familyName>
    </creator>
    <creator>
      <creatorName>Kerimova, T</creatorName>
      <givenName>T</givenName>
      <familyName>Kerimova</familyName>
    </creator>
  </creators>
  <titles>
    <title>Raman Scattering In Cdga2Se4 Under Pressure</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2003</publicationYear>
  <dates>
    <date dateType="Issued">2003-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/95153</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1002/pssb.200301579</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">The Raman scattering spectra of CdGa2Se4 under pressure were investigated at 300 K up to 20.9 GPa. TO as well as LO modes were observed. Two stages were observed in the pressure dependences of Raman bands. Such a behaviour was attributed to the order-disorder phase transition in the cation sublattice. A first-order phase transition under pressure was observed at 20.2 GPa. Using the Harrison-Keating model of the lattice dynamics modified for crystals with the tetragonal structure, the bulk modulus B and the mode-Gruneisen parameters Gamma(i) were determined for the first time. It is shown that a better agreement between the experimental and calculated values of Gamma(i) is observed if one takes into consideration the different behaviour with pressure for the bond-bending and the bond-stretching parameters, which determine the low-(lower than 140 cm(-1)) and high-(higher than 140 cm(-1)) frequency phonons, respectively.</description>
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