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Mitani, T; Naitou, T; Matsuishi, K; Onari, S; Allakhverdiev, K; Gashimzade, F; Kerimova, T
{ "DOI": "10.1002/pssb.200301579", "abstract": "The Raman scattering spectra of CdGa2Se4 under pressure were investigated at 300 K up to 20.9 GPa. TO as well as LO modes were observed. Two stages were observed in the pressure dependences of Raman bands. Such a behaviour was attributed to the order-disorder phase transition in the cation sublattice. A first-order phase transition under pressure was observed at 20.2 GPa. Using the Harrison-Keating model of the lattice dynamics modified for crystals with the tetragonal structure, the bulk modulus B and the mode-Gruneisen parameters Gamma(i) were determined for the first time. It is shown that a better agreement between the experimental and calculated values of Gamma(i) is observed if one takes into consideration the different behaviour with pressure for the bond-bending and the bond-stretching parameters, which determine the low-(lower than 140 cm(-1)) and high-(higher than 140 cm(-1)) frequency phonons, respectively.", "author": [ { "family": "Mitani", "given": " T" }, { "family": "Naitou", "given": " T" }, { "family": "Matsuishi", "given": " K" }, { "family": "Onari", "given": " S" }, { "family": "Allakhverdiev", "given": " K" }, { "family": "Gashimzade", "given": " F" }, { "family": "Kerimova", "given": " T" } ], "container_title": "PHYSICA STATUS SOLIDI B-BASIC RESEARCH", "id": "95153", "issue": "2", "issued": { "date-parts": [ [ 2003, 1, 1 ] ] }, "page": "321-325", "title": "Raman scattering in CdGa2Se4 under pressure", "type": "article-journal", "volume": "235" }
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