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Critical behavior of thermal phase transitions of iota-carrageenan in CaCl2 solution

Ozbek, Haluk; Pekcan, Onder


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{
  "DOI": "10.1016/j.physa.2005.09.073", 
  "abstract": "In situ photon transmission method was applied to study thermal phase transitions of t-carrageenan in CaCl2 solution. Coil-to-helix (c-h) and helix-to-dimer (h-d) transitions were detected upon cooling. An extra dimer-to-dimer (d-d) transition was observed as well during cooling at low-temperature region. Upon heating only dimer-to-helix (d-h) and helix-to-coil (h-c) transitions were detected. Photon transmission intensity, I-tr was monitored against temperature to determine several phase transitions and transition temperatures. It was observed that the c-h transition in i-carrageenan-CaCl2 system performs a crossover between 3D percolation to classical theory. Upon heating, the specific heat exponent over the d-h transition was extracted from the transmitted intensity data and was found to be 0.045. (c) 2005 Elsevier B.V. All rights reserved.", 
  "author": [
    {
      "family": "Ozbek", 
      "given": " Haluk"
    }, 
    {
      "family": "Pekcan", 
      "given": " Onder"
    }
  ], 
  "container_title": "PHYSICA A-STATISTICAL MECHANICS AND ITS APPLICATIONS", 
  "id": "95077", 
  "issued": {
    "date-parts": [
      [
        2006, 
        1, 
        1
      ]
    ]
  }, 
  "page": "69-78", 
  "title": "Critical behavior of thermal phase transitions of iota-carrageenan in CaCl2 solution", 
  "type": "article-journal", 
  "volume": "367"
}
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