1 Ocak 2015 Dergi makalesi Açık Erişim

Vatansever, Alican; Inan, Tulay Y.; Dogan, Hacer; Sirkecioglu, Ahmet

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/90771</identifier>
  <creators>
    <creator>
      <creatorName>Vatansever, Alican</creatorName>
      <givenName>Alican</givenName>
      <familyName>Vatansever</familyName>
      <affiliation>TUBITAK Marmara Res Ctr, Inst Chem, TR-41470 Gebze, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Inan, Tulay Y.</creatorName>
      <givenName>Tulay Y.</givenName>
      <familyName>Inan</familyName>
      <affiliation>Saudi Aramco, Dhahran 31311, Saudi Arabia</affiliation>
    </creator>
    <creator>
      <creatorName>Dogan, Hacer</creatorName>
      <givenName>Hacer</givenName>
      <familyName>Dogan</familyName>
      <affiliation>TUBITAK Marmara Res Ctr, Inst Chem, TR-41470 Gebze, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Sirkecioglu, Ahmet</creatorName>
      <givenName>Ahmet</givenName>
      <familyName>Sirkecioglu</familyName>
      <affiliation>Istanbul Tech Univ, Dept Chem &amp; Met, TR-34469 Istanbul, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Synthesis Of Poly(Butyl Acrylate-Co-Methyl Methacrylate)/Montmorillonite Waterborne Nanocomposite Via Semibatch Emulsion Polymerization</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2015</publicationYear>
  <dates>
    <date dateType="Issued">2015-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/90771</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1002/app.42373</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">Poly(butyl acrylate-co-methyl methacrylate)-montmorillonite (MMT) waterborne nanocomposites were successfully synthesized by semibatch emulsion polymerization. The syntheses of the nanocomposites were performed in presence of sodium montmorillonite (Na-MMT) and organically modified montmorillonite (O-MMT). O-MMT was used directly after the modification of Na-MMT with dimethyl dioctadecyl ammonium chloride. Both Na-MMT and O-MMT were sonified to obtain nanocomposites with 47 wt % solids and 3 wt % Na-MMT or O-MMT content. Average particle sizes of Na-MMT nanocomposites were measured as 110-150 nm while O-MMT nanocomposites were measured as 200-350 nm. Both Na-MMT and O-MMT increased thermal, mechanical, and barrier properties (water vapor and oxygen permeability) of the pristine copolymer explicitly. X-ray diffraction and transmission electron microscope studies show that exfoliated morphology was obtained. The gloss values of O-MMT nanocomposites were found to be higher than that of the pristine copolymer. (c) 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42373.</description>
  </descriptions>
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