1 Ocak 2015 Dergi makalesi Açık Erişim

Vatansever, Alican; Inan, Tulay Y.; Dogan, Hacer; Sirkecioglu, Ahmet

Citation Style Language JSON

{
  "DOI": "10.1002/app.42373", 
  "abstract": "Poly(butyl acrylate-co-methyl methacrylate)-montmorillonite (MMT) waterborne nanocomposites were successfully synthesized by semibatch emulsion polymerization. The syntheses of the nanocomposites were performed in presence of sodium montmorillonite (Na-MMT) and organically modified montmorillonite (O-MMT). O-MMT was used directly after the modification of Na-MMT with dimethyl dioctadecyl ammonium chloride. Both Na-MMT and O-MMT were sonified to obtain nanocomposites with 47 wt % solids and 3 wt % Na-MMT or O-MMT content. Average particle sizes of Na-MMT nanocomposites were measured as 110-150 nm while O-MMT nanocomposites were measured as 200-350 nm. Both Na-MMT and O-MMT increased thermal, mechanical, and barrier properties (water vapor and oxygen permeability) of the pristine copolymer explicitly. X-ray diffraction and transmission electron microscope studies show that exfoliated morphology was obtained. The gloss values of O-MMT nanocomposites were found to be higher than that of the pristine copolymer. (c) 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42373.", 
  "author": [
    {
      "family": "Vatansever", 
      "given": " Alican"
    }, 
    {
      "family": "Inan", 
      "given": " Tulay Y."
    }, 
    {
      "family": "Dogan", 
      "given": " Hacer"
    }, 
    {
      "family": "Sirkecioglu", 
      "given": " Ahmet"
    }
  ], 
  "container_title": "JOURNAL OF APPLIED POLYMER SCIENCE", 
  "id": "90771", 
  "issue": "32", 
  "issued": {
    "date-parts": [
      [
        2015, 
        1, 
        1
      ]
    ]
  }, 
  "title": "Synthesis of poly(butyl acrylate-co-methyl methacrylate)/montmorillonite waterborne nanocomposite via semibatch emulsion polymerization", 
  "type": "article-journal", 
  "volume": "132"
}