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Novel organoboron compounds derived from thieno[3,2-b]thiophene and triphenylamine units for OLED devices

Turkoglu, G.; Cinar, M. E.; Buyruk, A.; Tekin, E.; Mucur, S. P.; Kaya, K.; Ozturk, T.


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        "affiliation": "Istanbul Tech Univ, Fac Sci, Dept Chem, TR-34469 Istanbul, Turkey", 
        "name": "Turkoglu, G."
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      {
        "affiliation": "Istanbul Tech Univ, Fac Sci, Dept Chem, TR-34469 Istanbul, Turkey", 
        "name": "Cinar, M. E."
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      {
        "affiliation": "Istanbul Tech Univ, Fac Sci, Dept Chem, TR-34469 Istanbul, Turkey", 
        "name": "Buyruk, A."
      }, 
      {
        "affiliation": "TUBITAK MAM, TR-41470 Gebze, Kocaeli, Turkey", 
        "name": "Tekin, E."
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      {
        "affiliation": "TUBITAK MAM, TR-41470 Gebze, Kocaeli, Turkey", 
        "name": "Mucur, S. P."
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      {
        "affiliation": "Istanbul Tech Univ, Fac Sci, Dept Chem, TR-34469 Istanbul, Turkey", 
        "name": "Kaya, K."
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    "description": "Two novel D-A (donor-acceptor) and one D-A-D small molecules containing mesitylborane as an acceptor and triphenylamine as a donor, linked through a thieno[3,2-b]thiophene p-conjugated spacer, are synthesized and characterized. Their photo- and electrochemical properties were investigated by experimental and computational studies. The emission quantum efficiencies were determined to be between 46% and 68% in THF. Their solid-state quantum yields were recorded up to 42%. The fabricated electroluminescent devices as emitting materials showed sky-blue to yellowish green emissions. Their devices exhibit high performance with a turn-on voltage, maximal brightness, and highest luminescence efficiency of up to 4.0 V, 1200 cd m(-2) and 1.13 cd A(-1), respectively. These results pave new avenues for the future molecules possessing D and A units connected via fused thiophenes.", 
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