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Novel organoboron compounds derived from thieno[3,2-b]thiophene and triphenylamine units for OLED devices

Turkoglu, G.; Cinar, M. E.; Buyruk, A.; Tekin, E.; Mucur, S. P.; Kaya, K.; Ozturk, T.


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{
  "DOI": "10.1039/c6tc01285j", 
  "abstract": "Two novel D-A (donor-acceptor) and one D-A-D small molecules containing mesitylborane as an acceptor and triphenylamine as a donor, linked through a thieno[3,2-b]thiophene p-conjugated spacer, are synthesized and characterized. Their photo- and electrochemical properties were investigated by experimental and computational studies. The emission quantum efficiencies were determined to be between 46% and 68% in THF. Their solid-state quantum yields were recorded up to 42%. The fabricated electroluminescent devices as emitting materials showed sky-blue to yellowish green emissions. Their devices exhibit high performance with a turn-on voltage, maximal brightness, and highest luminescence efficiency of up to 4.0 V, 1200 cd m(-2) and 1.13 cd A(-1), respectively. These results pave new avenues for the future molecules possessing D and A units connected via fused thiophenes.", 
  "author": [
    {
      "family": "Turkoglu", 
      "given": " G."
    }, 
    {
      "family": "Cinar", 
      "given": " M. E."
    }, 
    {
      "family": "Buyruk", 
      "given": " A."
    }, 
    {
      "family": "Tekin", 
      "given": " E."
    }, 
    {
      "family": "Mucur", 
      "given": " S. P."
    }, 
    {
      "family": "Kaya", 
      "given": " K."
    }, 
    {
      "family": "Ozturk", 
      "given": " T."
    }
  ], 
  "container_title": "JOURNAL OF MATERIALS CHEMISTRY C", 
  "id": "90283", 
  "issue": "25", 
  "issued": {
    "date-parts": [
      [
        2016, 
        1, 
        1
      ]
    ]
  }, 
  "page": "6045-6053", 
  "title": "Novel organoboron compounds derived from thieno[3,2-b]thiophene and triphenylamine units for OLED devices", 
  "type": "article-journal", 
  "volume": "4"
}
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