1 Ocak 2013 Dergi makalesi Açık Erişim

Un, Ilker; Ibisoglu, Hanife; Un, Sule Sahin; Cosut, Bunyemin; Kilic, Adem

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        "name": "Un, Ilker"
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      {
        "affiliation": "Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Turkey", 
        "name": "Ibisoglu, Hanife"
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      {
        "affiliation": "Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Turkey", 
        "name": "Un, Sule Sahin"
      }, 
      {
        "affiliation": "Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Turkey", 
        "name": "Cosut, Bunyemin"
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      {
        "affiliation": "Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Turkey", 
        "name": "Kilic, Adem"
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    "description": "In this study, phenoxy-adamantane substituted cyclophosphazene compounds (5-8) were synthesized in three steps. Firstly; adamantane derivatives (1 and 2) containing alkyne groups were prepared. Secondly; 2,2,4,4,6,6-hexzakis-(2'-azido-1'-ethoxy)-cyclotriphosphazatriene (3) and 2,2,4,4,6,6,8,8-octakis-(2'-azido-1'-ethoxy)-cyclotetraphosphazatetraene (4) were synthesized from the nucleophilic substitutions of 2-azido-1-ethanol with trimer (N3P3Cl6) and tetramer (N4P4Cl8) in THF respectively. Thirdly; cyclophosphazenes containing adamantane units (5-8) were obtained by the Cu(I) catalyzed click reactions of cyclophosphazenes (3 and 4) with compounds 1 and 2. The structural investigations of newly synthesized compounds 1-8 were evaluated by elemental analysis and FT-IR (ATR), mass spectrometry, H-1, C-13, H-1-C-13 HSQC (for 6) and P-31 NMR (for 3-8) spectroscopies. Compound 1-8 were also reported for the first time. The thermal and photophysical properties of 5-8 were investigated. (C) 2013 Elsevier B. V. All rights reserved.", 
    "doi": "10.1016/j.ica.2013.01.028", 
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      "pages": "219-226", 
      "title": "INORGANICA CHIMICA ACTA", 
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    "title": "Syntheses, characterizations, thermal and photophysical properties of cyclophosphazenes containing adamantane units"
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