1 Ocak 2013 Dergi makalesi Açık Erişim

Un, Ilker; Ibisoglu, Hanife; Un, Sule Sahin; Cosut, Bunyemin; Kilic, Adem

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/89319</identifier>
  <creators>
    <creator>
      <creatorName>Un, Ilker</creatorName>
      <givenName>Ilker</givenName>
      <familyName>Un</familyName>
    </creator>
    <creator>
      <creatorName>Ibisoglu, Hanife</creatorName>
      <givenName>Hanife</givenName>
      <familyName>Ibisoglu</familyName>
      <affiliation>Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Un, Sule Sahin</creatorName>
      <givenName>Sule Sahin</givenName>
      <familyName>Un</familyName>
      <affiliation>Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Cosut, Bunyemin</creatorName>
      <givenName>Bunyemin</givenName>
      <familyName>Cosut</familyName>
      <affiliation>Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Kilic, Adem</creatorName>
      <givenName>Adem</givenName>
      <familyName>Kilic</familyName>
      <affiliation>Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Syntheses, Characterizations, Thermal And Photophysical Properties Of Cyclophosphazenes Containing Adamantane Units</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2013</publicationYear>
  <dates>
    <date dateType="Issued">2013-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/89319</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.ica.2013.01.028</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">In this study, phenoxy-adamantane substituted cyclophosphazene compounds (5-8) were synthesized in three steps. Firstly; adamantane derivatives (1 and 2) containing alkyne groups were prepared. Secondly; 2,2,4,4,6,6-hexzakis-(2'-azido-1'-ethoxy)-cyclotriphosphazatriene (3) and 2,2,4,4,6,6,8,8-octakis-(2'-azido-1'-ethoxy)-cyclotetraphosphazatetraene (4) were synthesized from the nucleophilic substitutions of 2-azido-1-ethanol with trimer (N3P3Cl6) and tetramer (N4P4Cl8) in THF respectively. Thirdly; cyclophosphazenes containing adamantane units (5-8) were obtained by the Cu(I) catalyzed click reactions of cyclophosphazenes (3 and 4) with compounds 1 and 2. The structural investigations of newly synthesized compounds 1-8 were evaluated by elemental analysis and FT-IR (ATR), mass spectrometry, H-1, C-13, H-1-C-13 HSQC (for 6) and P-31 NMR (for 3-8) spectroscopies. Compound 1-8 were also reported for the first time. The thermal and photophysical properties of 5-8 were investigated. (C) 2013 Elsevier B. V. All rights reserved.</description>
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