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Dehydration, Water Vapor Adsorption and Desorption Behavior of Zn[B3O3(OH)(5)] center dot H2O and Zn[B3O4(OH)(3)]

Alp, Burcu; Gonen, Mehmet; Savrik, Sevdiye Atakul; Balkose, Devrim; Ulku, Semra


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{
  "DOI": "10.1080/07373937.2012.701258", 
  "abstract": "The dehydration behaviors of two different hydrated zinc borate species, Zn[B3O3(OH)(5)] center dot H2O and Zn[B3O4(OH)(3)], which are industrially important flame retardants, were studied by thermal gravimetric(TG) analysis and in situ diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy. Dehydration onset temperatures of Zn[B3O3(OH)(5)] center dot H2O and Zn[B3O4(OH)(3)] were 129 and 320 degrees C, respectively, at a 10 degrees C/min ramp rate. A very small amount of boric acid was volatilized in addition to water vapor when both samples were heated at 250 degrees C. A significant amount of water vapor was adsorbed by Zn[B3O3(OH)(5)] center dot H2O from air at 25 degrees C. However, Zn[B3O4(OH)(3)] adsorbed a very small amount of water under the same conditions. Both zinc borates did not have a tendency to cake during storage.", 
  "author": [
    {
      "family": "Alp", 
      "given": " Burcu"
    }, 
    {
      "family": "Gonen", 
      "given": " Mehmet"
    }, 
    {
      "family": "Savrik", 
      "given": " Sevdiye Atakul"
    }, 
    {
      "family": "Balkose", 
      "given": " Devrim"
    }, 
    {
      "family": "Ulku", 
      "given": " Semra"
    }
  ], 
  "container_title": "DRYING TECHNOLOGY", 
  "id": "84349", 
  "issue": "14", 
  "issued": {
    "date-parts": [
      [
        2012, 
        1, 
        1
      ]
    ]
  }, 
  "page": "1610-1620", 
  "title": "Dehydration, Water Vapor Adsorption and Desorption Behavior of Zn[B3O3(OH)(5)] center dot H2O and Zn[B3O4(OH)(3)]", 
  "type": "article-journal", 
  "volume": "30"
}
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