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Photoelectrochemical performance of thermally sulfurized CdxZn1-xS photoanode: Enhancement with reduced graphene oxide support

Ayaz, RanaMuhammad Zunain; Akyuz, Duygu; Uguz, Ozlem; Tansik, Irem; Sarioglu, Cevat; Karaca, Fatma; Ozkaya, Ali Riza; Koca, Atif


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        "affiliation": "Marmara Univ, Fac Engn, Dept Chem Engn, TR-34722 Istanbul, Turkey", 
        "name": "Ayaz, RanaMuhammad Zunain"
      }, 
      {
        "affiliation": "Marmara Univ, Fac Sci & Letters, Dept Chem, TR-34722 Istanbul, Turkey", 
        "name": "Akyuz, Duygu"
      }, 
      {
        "affiliation": "Marmara Univ, Fac Engn, Dept Chem Engn, TR-34722 Istanbul, Turkey", 
        "name": "Uguz, Ozlem"
      }, 
      {
        "affiliation": "Marmara Univ, Fac Engn, Dept Chem Engn, TR-34722 Istanbul, Turkey", 
        "name": "Tansik, Irem"
      }, 
      {
        "affiliation": "Marmara Univ, Fac Engn, Dept Met & Mat Engn, TR-34722 Istanbul, Turkey", 
        "name": "Sarioglu, Cevat"
      }, 
      {
        "affiliation": "Marmara Univ, Fac Engn, Dept Chem Engn, TR-34722 Istanbul, Turkey", 
        "name": "Karaca, Fatma"
      }, 
      {
        "affiliation": "Marmara Univ, Fac Sci & Letters, Dept Chem, TR-34722 Istanbul, Turkey", 
        "name": "Ozkaya, Ali Riza"
      }, 
      {
        "affiliation": "Marmara Univ, Fac Engn, Dept Chem Engn, TR-34722 Istanbul, Turkey", 
        "name": "Koca, Atif"
      }
    ], 
    "description": "In this study, photoelectrochemical performance of reduced graphene oxide (RGO)-CdxZn1-xS compos-ites, which were synthesized through a novel two-steps thermal sulfurization process by using elemental sulfur, was reported. This is the first time that the two-step thermal sulfurization process with elemental sulfur for the preparation of photoanode based on RGO-CdxZn1-xS. The electrodes exhibited high photostability and photocurrent response in the presence of visible light. The presence of RGO in CdxZn1-xS as electron collector and transporter increased the photocurrents approximately 40%. Among the RGOCdxZn1-xS composites, RGO-CdS photoanode yielded an extremely high photocurrent density of 6.5 mAcm(-2) with the rate of hydrogen production rate of 551.1mmolh(-1)cm(-2). This value of photocurrent density is almost 89% of its theoretical value. This is the maximum attained photocurrent density with superior stability in comparison with related literature. (c) 2020 Elsevier Ltd. All rights reserved.", 
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      "pages": "182-195", 
      "title": "RENEWABLE ENERGY", 
      "volume": "162"
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    "title": "Photoelectrochemical performance of thermally sulfurized CdxZn1-xS photoanode: Enhancement with reduced graphene oxide support"
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