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Photoelectrochemical performance of thermally sulfurized CdxZn1-xS photoanode: Enhancement with reduced graphene oxide support

Ayaz, RanaMuhammad Zunain; Akyuz, Duygu; Uguz, Ozlem; Tansik, Irem; Sarioglu, Cevat; Karaca, Fatma; Ozkaya, Ali Riza; Koca, Atif


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{
  "DOI": "10.1016/j.renene.2020.07.102", 
  "abstract": "In this study, photoelectrochemical performance of reduced graphene oxide (RGO)-CdxZn1-xS compos-ites, which were synthesized through a novel two-steps thermal sulfurization process by using elemental sulfur, was reported. This is the first time that the two-step thermal sulfurization process with elemental sulfur for the preparation of photoanode based on RGO-CdxZn1-xS. The electrodes exhibited high photostability and photocurrent response in the presence of visible light. The presence of RGO in CdxZn1-xS as electron collector and transporter increased the photocurrents approximately 40%. Among the RGOCdxZn1-xS composites, RGO-CdS photoanode yielded an extremely high photocurrent density of 6.5 mAcm(-2) with the rate of hydrogen production rate of 551.1mmolh(-1)cm(-2). This value of photocurrent density is almost 89% of its theoretical value. This is the maximum attained photocurrent density with superior stability in comparison with related literature. (c) 2020 Elsevier Ltd. All rights reserved.", 
  "author": [
    {
      "family": "Ayaz", 
      "given": " RanaMuhammad Zunain"
    }, 
    {
      "family": "Akyuz", 
      "given": " Duygu"
    }, 
    {
      "family": "Uguz", 
      "given": " Ozlem"
    }, 
    {
      "family": "Tansik", 
      "given": " Irem"
    }, 
    {
      "family": "Sarioglu", 
      "given": " Cevat"
    }, 
    {
      "family": "Karaca", 
      "given": " Fatma"
    }, 
    {
      "family": "Ozkaya", 
      "given": " Ali Riza"
    }, 
    {
      "family": "Koca", 
      "given": " Atif"
    }
  ], 
  "container_title": "RENEWABLE ENERGY", 
  "id": "8365", 
  "issued": {
    "date-parts": [
      [
        2020, 
        1, 
        1
      ]
    ]
  }, 
  "page": "182-195", 
  "title": "Photoelectrochemical performance of thermally sulfurized CdxZn1-xS photoanode: Enhancement with reduced graphene oxide support", 
  "type": "article-journal", 
  "volume": "162"
}
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