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Nisanci, Bilal; Ganjehyan, Khadijeh; Metin, Onder; Dastan, Arif; Toeroek, Bela
<?xml version='1.0' encoding='utf-8'?> <resource xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://datacite.org/schema/kernel-4" xsi:schemaLocation="http://datacite.org/schema/kernel-4 http://schema.datacite.org/meta/kernel-4.1/metadata.xsd"> <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/77371</identifier> <creators> <creator> <creatorName>Nisanci, Bilal</creatorName> <givenName>Bilal</givenName> <familyName>Nisanci</familyName> </creator> <creator> <creatorName>Ganjehyan, Khadijeh</creatorName> <givenName>Khadijeh</givenName> <familyName>Ganjehyan</familyName> <affiliation>Ataturk Univ, Fac Sci, Dept Chem, TR-25240 Erzurum, Turkey</affiliation> </creator> <creator> <creatorName>Metin, Onder</creatorName> <givenName>Onder</givenName> <familyName>Metin</familyName> <affiliation>Ataturk Univ, Fac Sci, Dept Chem, TR-25240 Erzurum, Turkey</affiliation> </creator> <creator> <creatorName>Dastan, Arif</creatorName> <givenName>Arif</givenName> <familyName>Dastan</familyName> <affiliation>Ataturk Univ, Fac Sci, Dept Chem, TR-25240 Erzurum, Turkey</affiliation> </creator> <creator> <creatorName>Toeroek, Bela</creatorName> <givenName>Bela</givenName> <familyName>Toeroek</familyName> <affiliation>Univ Massachusetts, Dept Chem, Boston, MA 02125 USA</affiliation> </creator> </creators> <titles> <title>Graphene-Supported Nipd Alloy Nanoparticles: A Novel And Highly Efficient Heterogeneous Catalyst System For The Reductive Amination Of Aldehydes</title> </titles> <publisher>Aperta</publisher> <publicationYear>2015</publicationYear> <dates> <date dateType="Issued">2015-01-01</date> </dates> <resourceType resourceTypeGeneral="Text">Journal article</resourceType> <alternateIdentifiers> <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/77371</alternateIdentifier> </alternateIdentifiers> <relatedIdentifiers> <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.molcata.2015.08.022</relatedIdentifier> </relatedIdentifiers> <rightsList> <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights> <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights> </rightsList> <descriptions> <description descriptionType="Abstract">A novel and highly efficient heterogeneous catalytic reductive amination of aldehydes is described. The recently developed graphene supported NiPd alloy nanoparticle (G-NiPd) catalyst using ammonia borane (AB) as a green, stable and safe hydrogen donor was used in a water/methanol mixture (v/v=2/3) under ambient conditions. The catalytic system was successfully applied in the reductive amination of various substituted aldehydes with amines and the corresponding products were obtained in (up to) 99% yield in 6 h. The G-NiPd catalyst could be recycled up to five times without any significant loss in the product yield. (C) 2015 Elsevier B.V. All rights reserved.</description> </descriptions> </resource>
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