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Graphene-supported NiPd alloy nanoparticles: A novel and highly efficient heterogeneous catalyst system for the reductive amination of aldehydes

Nisanci, Bilal; Ganjehyan, Khadijeh; Metin, Onder; Dastan, Arif; Toeroek, Bela


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/77371</identifier>
  <creators>
    <creator>
      <creatorName>Nisanci, Bilal</creatorName>
      <givenName>Bilal</givenName>
      <familyName>Nisanci</familyName>
    </creator>
    <creator>
      <creatorName>Ganjehyan, Khadijeh</creatorName>
      <givenName>Khadijeh</givenName>
      <familyName>Ganjehyan</familyName>
      <affiliation>Ataturk Univ, Fac Sci, Dept Chem, TR-25240 Erzurum, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Metin, Onder</creatorName>
      <givenName>Onder</givenName>
      <familyName>Metin</familyName>
      <affiliation>Ataturk Univ, Fac Sci, Dept Chem, TR-25240 Erzurum, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Dastan, Arif</creatorName>
      <givenName>Arif</givenName>
      <familyName>Dastan</familyName>
      <affiliation>Ataturk Univ, Fac Sci, Dept Chem, TR-25240 Erzurum, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Toeroek, Bela</creatorName>
      <givenName>Bela</givenName>
      <familyName>Toeroek</familyName>
      <affiliation>Univ Massachusetts, Dept Chem, Boston, MA 02125 USA</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Graphene-Supported Nipd Alloy Nanoparticles: A Novel And Highly Efficient Heterogeneous Catalyst System For The Reductive Amination Of Aldehydes</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2015</publicationYear>
  <dates>
    <date dateType="Issued">2015-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/77371</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.molcata.2015.08.022</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">A novel and highly efficient heterogeneous catalytic reductive amination of aldehydes is described. The recently developed graphene supported NiPd alloy nanoparticle (G-NiPd) catalyst using ammonia borane (AB) as a green, stable and safe hydrogen donor was used in a water/methanol mixture (v/v=2/3) under ambient conditions. The catalytic system was successfully applied in the reductive amination of various substituted aldehydes with amines and the corresponding products were obtained in (up to) 99% yield in 6 h. The G-NiPd catalyst could be recycled up to five times without any significant loss in the product yield. (C) 2015 Elsevier B.V. All rights reserved.</description>
  </descriptions>
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