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Graphene-supported NiPd alloy nanoparticles: A novel and highly efficient heterogeneous catalyst system for the reductive amination of aldehydes

Nisanci, Bilal; Ganjehyan, Khadijeh; Metin, Onder; Dastan, Arif; Toeroek, Bela


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{
  "DOI": "10.1016/j.molcata.2015.08.022", 
  "abstract": "A novel and highly efficient heterogeneous catalytic reductive amination of aldehydes is described. The recently developed graphene supported NiPd alloy nanoparticle (G-NiPd) catalyst using ammonia borane (AB) as a green, stable and safe hydrogen donor was used in a water/methanol mixture (v/v=2/3) under ambient conditions. The catalytic system was successfully applied in the reductive amination of various substituted aldehydes with amines and the corresponding products were obtained in (up to) 99% yield in 6 h. The G-NiPd catalyst could be recycled up to five times without any significant loss in the product yield. (C) 2015 Elsevier B.V. All rights reserved.", 
  "author": [
    {
      "family": "Nisanci", 
      "given": " Bilal"
    }, 
    {
      "family": "Ganjehyan", 
      "given": " Khadijeh"
    }, 
    {
      "family": "Metin", 
      "given": " Onder"
    }, 
    {
      "family": "Dastan", 
      "given": " Arif"
    }, 
    {
      "family": "Toeroek", 
      "given": " Bela"
    }
  ], 
  "container_title": "JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL", 
  "id": "77371", 
  "issued": {
    "date-parts": [
      [
        2015, 
        1, 
        1
      ]
    ]
  }, 
  "page": "191-197", 
  "title": "Graphene-supported NiPd alloy nanoparticles: A novel and highly efficient heterogeneous catalyst system for the reductive amination of aldehydes", 
  "type": "article-journal", 
  "volume": "409"
}
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