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Chiral polymorphism in new imine based rod-like liquid crystals

Caglar, Fatma Pinar; Akdas-Kilic, Huriye; Ocak, Hale; Eran, Belkiz Bilgin


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/7713</identifier>
  <creators>
    <creator>
      <creatorName>Caglar, Fatma Pinar</creatorName>
      <givenName>Fatma Pinar</givenName>
      <familyName>Caglar</familyName>
      <affiliation>Yildiz Tech Univ, Dept Chem, TR-34220 Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Akdas-Kilic, Huriye</creatorName>
      <givenName>Huriye</givenName>
      <familyName>Akdas-Kilic</familyName>
    </creator>
    <creator>
      <creatorName>Ocak, Hale</creatorName>
      <givenName>Hale</givenName>
      <familyName>Ocak</familyName>
      <affiliation>Yildiz Tech Univ, Dept Chem, TR-34220 Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Eran, Belkiz Bilgin</creatorName>
      <givenName>Belkiz Bilgin</givenName>
      <familyName>Eran</familyName>
      <affiliation>Yildiz Tech Univ, Dept Chem, TR-34220 Istanbul, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Chiral Polymorphism In New Imine Based Rod-Like Liquid Crystals</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2020</publicationYear>
  <dates>
    <date dateType="Issued">2020-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/7713</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.molstruc.2020.128755</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">New imine based rod-like compounds, composed of three-benzene-ring molecular core linked with azomethine as well as ester groups and terminated with (S)-3,7-dimethyloctyloxy chiral unit at one side have been synthesized. The other terminal position has been varied by using n-octyloxy/decyloxy/dodecyloxy groups to reveal chain length effect on mesophase behavior. The liquid crystalline properties of the new compounds have been investigated by polarizing optical microscopy, differential scanning calorimetry and electro-optic studies. The novel chiral calamitics derived from Schiff base or salicylaldimine-core show a chiral polymorphism comprising of blue phase and chiral nematic as well as smectics such as chiral tilted smectic and unidentified smectic mesophase. (C) 2020 Elsevier B.V. All rights reserved.</description>
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