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Chiral polymorphism in new imine based rod-like liquid crystals

Caglar, Fatma Pinar; Akdas-Kilic, Huriye; Ocak, Hale; Eran, Belkiz Bilgin


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{
  "DOI": "10.1016/j.molstruc.2020.128755", 
  "abstract": "New imine based rod-like compounds, composed of three-benzene-ring molecular core linked with azomethine as well as ester groups and terminated with (S)-3,7-dimethyloctyloxy chiral unit at one side have been synthesized. The other terminal position has been varied by using n-octyloxy/decyloxy/dodecyloxy groups to reveal chain length effect on mesophase behavior. The liquid crystalline properties of the new compounds have been investigated by polarizing optical microscopy, differential scanning calorimetry and electro-optic studies. The novel chiral calamitics derived from Schiff base or salicylaldimine-core show a chiral polymorphism comprising of blue phase and chiral nematic as well as smectics such as chiral tilted smectic and unidentified smectic mesophase. (C) 2020 Elsevier B.V. All rights reserved.", 
  "author": [
    {
      "family": "Caglar", 
      "given": " Fatma Pinar"
    }, 
    {
      "family": "Akdas-Kilic", 
      "given": " Huriye"
    }, 
    {
      "family": "Ocak", 
      "given": " Hale"
    }, 
    {
      "family": "Eran", 
      "given": " Belkiz Bilgin"
    }
  ], 
  "container_title": "JOURNAL OF MOLECULAR STRUCTURE", 
  "id": "7713", 
  "issued": {
    "date-parts": [
      [
        2020, 
        1, 
        1
      ]
    ]
  }, 
  "title": "Chiral polymorphism in new imine based rod-like liquid crystals", 
  "type": "article-journal", 
  "volume": "1220"
}
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