1 Ocak 2015 Dergi makalesi Açık Erişim

Yardan, Alper; Hopa, Cigdem; Yahsi, Yasemin; Karahan, Ahmet; Kara, Hulya; Kurtaran, Raif

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    "creators": [
      {
        "affiliation": "Balikesir Univ, Dursunbey Vocat Sch, Dept Property Protect & Safety, TR-10800 Balikesir, Turkey", 
        "name": "Yardan, Alper"
      }, 
      {
        "affiliation": "Balikesir Univ, Fac Art & Sci, Dept Chem, TR-10145 Balikesir, Turkey", 
        "name": "Hopa, Cigdem"
      }, 
      {
        "affiliation": "Balikesir Univ, Fac Art & Sci, Dept Phys, TR-10145 Balikesir, Turkey", 
        "name": "Yahsi, Yasemin"
      }, 
      {
        "affiliation": "Suleyman Demirel Univ, Sutculer Prof Dr Hasan Gurbuz Vocat Sch, Dept Property Protect & Safety, TR-32950 Isparta, Turkey", 
        "name": "Karahan, Ahmet"
      }, 
      {
        "affiliation": "Balikesir Univ, Fac Art & Sci, Dept Phys, TR-10145 Balikesir, Turkey", 
        "name": "Kara, Hulya"
      }, 
      {
        "affiliation": "Akdeniz Univ, Alanya Engn Fac, TR-07400 Antalya, Turkey", 
        "name": "Kurtaran, Raif"
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    "description": "Two new heterodinuclear Schiff base complexes, [Hg(L)NiCl2(DMF)(2)] 1, and [Zn(L)NiCl2(DMF)(2)] 2, where H2L = N,N'-bis(salicylidene)-1,3-diaminopropane and DMF = dimethylformamide have been synthesized and characterized using elemental analysis, IR spectroscopy, thermal analysis and X-ray diffraction. Structural studies on 1 and 2 reveal the presence of a heterodinuclear [(NiHgII)-Hg-II] unit and [(ZnNiII)-Ni-II] in which the central metal ions are connected to each other by two phenolate oxygen bridges. For complex 1 the Ni(II) ion adopts an elongated octahedral geometry (NiN2O4) while the Hg(II) ion assumes a distorted tetrahedral arrangement (HgO2Cl2) whereas for complex 2 the Zn(II) ion adopts an elongated octahedral geometry (ZnN2O4) while the Ni(II) ion assumes a distorted tetrahedral arrangement (NiO2Cl2). There are intermolecular C-H center dot center dot center dot Cl-M interactions among the dinuclear complexes which are interconnected for 1 and 2. These intermolecular interactions result in the formation of a three dimensional structure for 1 and one dimensional zig-zag chains for 2. (C) 2014 Elsevier B.V. All rights reserved.", 
    "doi": "10.1016/j.saa.2014.08.091", 
    "has_grant": false, 
    "journal": {
      "pages": "351-356", 
      "title": "SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY", 
      "volume": "137"
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    "publication_date": "2015-01-01", 
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      "title": "Dergi makalesi", 
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    "title": "Two new heterodinuclear Schiff base complexes: Synthesis, crystal structure and thermal studies"
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