1 Ocak 2015 Dergi makalesi Açık Erişim

Yardan, Alper; Hopa, Cigdem; Yahsi, Yasemin; Karahan, Ahmet; Kara, Hulya; Kurtaran, Raif

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/76955</identifier>
  <creators>
    <creator>
      <creatorName>Yardan, Alper</creatorName>
      <givenName>Alper</givenName>
      <familyName>Yardan</familyName>
      <affiliation>Balikesir Univ, Dursunbey Vocat Sch, Dept Property Protect &amp; Safety, TR-10800 Balikesir, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Hopa, Cigdem</creatorName>
      <givenName>Cigdem</givenName>
      <familyName>Hopa</familyName>
      <affiliation>Balikesir Univ, Fac Art &amp; Sci, Dept Chem, TR-10145 Balikesir, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Yahsi, Yasemin</creatorName>
      <givenName>Yasemin</givenName>
      <familyName>Yahsi</familyName>
      <affiliation>Balikesir Univ, Fac Art &amp; Sci, Dept Phys, TR-10145 Balikesir, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Karahan, Ahmet</creatorName>
      <givenName>Ahmet</givenName>
      <familyName>Karahan</familyName>
      <affiliation>Suleyman Demirel Univ, Sutculer Prof Dr Hasan Gurbuz Vocat Sch, Dept Property Protect &amp; Safety, TR-32950 Isparta, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Kara, Hulya</creatorName>
      <givenName>Hulya</givenName>
      <familyName>Kara</familyName>
      <affiliation>Balikesir Univ, Fac Art &amp; Sci, Dept Phys, TR-10145 Balikesir, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Kurtaran, Raif</creatorName>
      <givenName>Raif</givenName>
      <familyName>Kurtaran</familyName>
      <affiliation>Akdeniz Univ, Alanya Engn Fac, TR-07400 Antalya, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Two New Heterodinuclear Schiff Base Complexes: Synthesis, Crystal Structure And Thermal Studies</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2015</publicationYear>
  <dates>
    <date dateType="Issued">2015-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/76955</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.saa.2014.08.091</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">Two new heterodinuclear Schiff base complexes, [Hg(L)NiCl2(DMF)(2)] 1, and [Zn(L)NiCl2(DMF)(2)] 2, where H2L = N,N'-bis(salicylidene)-1,3-diaminopropane and DMF = dimethylformamide have been synthesized and characterized using elemental analysis, IR spectroscopy, thermal analysis and X-ray diffraction. Structural studies on 1 and 2 reveal the presence of a heterodinuclear [(NiHgII)-Hg-II] unit and [(ZnNiII)-Ni-II] in which the central metal ions are connected to each other by two phenolate oxygen bridges. For complex 1 the Ni(II) ion adopts an elongated octahedral geometry (NiN2O4) while the Hg(II) ion assumes a distorted tetrahedral arrangement (HgO2Cl2) whereas for complex 2 the Zn(II) ion adopts an elongated octahedral geometry (ZnN2O4) while the Ni(II) ion assumes a distorted tetrahedral arrangement (NiO2Cl2). There are intermolecular C-H center dot center dot center dot Cl-M interactions among the dinuclear complexes which are interconnected for 1 and 2. These intermolecular interactions result in the formation of a three dimensional structure for 1 and one dimensional zig-zag chains for 2. (C) 2014 Elsevier B.V. All rights reserved.</description>
  </descriptions>
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