1 Ocak 2019 Dergi makalesi Açık Erişim

Burgaz, Engin; Erciyes, Ayse; Andac, Muberra; Andac, Omer

JSON-LD (schema.org)

{
  "@context": "https://schema.org/", 
  "@id": 72851, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "name": "Burgaz, Engin"
    }, 
    {
      "@type": "Person", 
      "name": "Erciyes, Ayse"
    }, 
    {
      "@type": "Person", 
      "name": "Andac, Muberra"
    }, 
    {
      "@type": "Person", 
      "name": "Andac, Omer"
    }
  ], 
  "datePublished": "2019-01-01", 
  "description": "Nano-sized metal organic framework-5 (MOF-5) was prepared in the presence of triethylamine (TEA) via consecutive combination of ultrasound (US) and microwave irradiation (MW) methods by exploiting the benefit of obtaining MOF-5 in very short reaction times (similar to 2 min) and high yields (similar to 95%). The surface area of MOF-5 was found to be 1203 m(2)/g. The highly crystalline structure of nano-sized MOF-5 was confirmed by XRD. Vibrational modes and thermal decomposition behavior of nano-sized MOF-5 were verified from ATR FT-IR and TGA results, respectively. Based on SEM and AFM results, MOF-5 nanoparticles are spherical in shape, and their sizes vary in the range of 20-80 nm. The high purity of nanosized MOF-5 was confirmed by XRD and EDS results. A very regular and homogenous distribution of MOF-5 nanoparticles with a size range of 20-30 nm within poly(ethylene oxide) (PEO) electrolyte was clearly observed from SEM results. The reason behind size reduction and homogenous distribution of nano-sized MOF-5 was stated as the elimination of any possible aggregation of MOF-5 nanoparticles due to favorable physical interactions between PEO and surface functional groups of MOF-5 during the solution casting process.", 
  "headline": "Synthesis and characterization of nano-sized metal organic framework-5 (MOF-5) by using consecutive combination of ultrasound and microwave irradiation methods", 
  "identifier": 72851, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Synthesis and characterization of nano-sized metal organic framework-5 (MOF-5) by using consecutive combination of ultrasound and microwave irradiation methods", 
  "url": "https://aperta.ulakbim.gov.tr/record/72851"
}