1 Ocak 2019 Dergi makalesi Açık Erişim

Burgaz, Engin; Erciyes, Ayse; Andac, Muberra; Andac, Omer

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/72851</identifier>
  <creators>
    <creator>
      <creatorName>Burgaz, Engin</creatorName>
      <givenName>Engin</givenName>
      <familyName>Burgaz</familyName>
    </creator>
    <creator>
      <creatorName>Erciyes, Ayse</creatorName>
      <givenName>Ayse</givenName>
      <familyName>Erciyes</familyName>
    </creator>
    <creator>
      <creatorName>Andac, Muberra</creatorName>
      <givenName>Muberra</givenName>
      <familyName>Andac</familyName>
    </creator>
    <creator>
      <creatorName>Andac, Omer</creatorName>
      <givenName>Omer</givenName>
      <familyName>Andac</familyName>
    </creator>
  </creators>
  <titles>
    <title>Synthesis And Characterization Of Nano-Sized Metal Organic Framework-5 (Mof-5) By Using Consecutive Combination Of Ultrasound And Microwave Irradiation Methods</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2019</publicationYear>
  <dates>
    <date dateType="Issued">2019-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/72851</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.ica.2018.10.014</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
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  <descriptions>
    <description descriptionType="Abstract">Nano-sized metal organic framework-5 (MOF-5) was prepared in the presence of triethylamine (TEA) via consecutive combination of ultrasound (US) and microwave irradiation (MW) methods by exploiting the benefit of obtaining MOF-5 in very short reaction times (similar to 2 min) and high yields (similar to 95%). The surface area of MOF-5 was found to be 1203 m(2)/g. The highly crystalline structure of nano-sized MOF-5 was confirmed by XRD. Vibrational modes and thermal decomposition behavior of nano-sized MOF-5 were verified from ATR FT-IR and TGA results, respectively. Based on SEM and AFM results, MOF-5 nanoparticles are spherical in shape, and their sizes vary in the range of 20-80 nm. The high purity of nanosized MOF-5 was confirmed by XRD and EDS results. A very regular and homogenous distribution of MOF-5 nanoparticles with a size range of 20-30 nm within poly(ethylene oxide) (PEO) electrolyte was clearly observed from SEM results. The reason behind size reduction and homogenous distribution of nano-sized MOF-5 was stated as the elimination of any possible aggregation of MOF-5 nanoparticles due to favorable physical interactions between PEO and surface functional groups of MOF-5 during the solution casting process.</description>
  </descriptions>
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