1 Ocak 2019 Dergi makalesi Açık Erişim

Kap, Zeynep; Karadas, Ferdi

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{
  "@context": "https://schema.org/", 
  "@id": 72841, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Bilkent Univ, Dept Chem, TR-06800 Ankara, Turkey", 
      "name": "Kap, Zeynep"
    }, 
    {
      "@type": "Person", 
      "name": "Karadas, Ferdi"
    }
  ], 
  "datePublished": "2019-01-01", 
  "description": "A facile synthesis for a photosensitizer-water oxidation catalyst (PS-WOC) dyad, which is connected through a polymeric platform, has been reported. The dyad assembly consists of a ruthenium-based chromophore and a cobalt-iron pentacyanoferrate coordination network as the water oxidation catalyst while poly(4-vinylpyridine) serves as the bridging group between two collaborating units. Photocatalytic experiments in the presence of an electron scavenger reveal that the dyad assembly maintains its activity for 6 h while the activity of a cobalt hexacyanoferrate and Ru(bpy)(3)(2+) couple decreases gradually and eventually decays after a 3 h catalytic experiment. Infrared and XPS studies performed on the post-catalytic powder sample confirm the stability of the dyad during the catalytic process.", 
  "headline": "Visible light-driven water oxidation with a ruthenium sensitizer and a cobalt-based catalyst connected with a polymeric platform", 
  "identifier": 72841, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Visible light-driven water oxidation with a ruthenium sensitizer and a cobalt-based catalyst connected with a polymeric platform", 
  "url": "https://aperta.ulakbim.gov.tr/record/72841"
}