Dergi makalesi Açık Erişim
Kap, Zeynep; Karadas, Ferdi
{ "DOI": "10.1039/c8fd00166a", "abstract": "A facile synthesis for a photosensitizer-water oxidation catalyst (PS-WOC) dyad, which is connected through a polymeric platform, has been reported. The dyad assembly consists of a ruthenium-based chromophore and a cobalt-iron pentacyanoferrate coordination network as the water oxidation catalyst while poly(4-vinylpyridine) serves as the bridging group between two collaborating units. Photocatalytic experiments in the presence of an electron scavenger reveal that the dyad assembly maintains its activity for 6 h while the activity of a cobalt hexacyanoferrate and Ru(bpy)(3)(2+) couple decreases gradually and eventually decays after a 3 h catalytic experiment. Infrared and XPS studies performed on the post-catalytic powder sample confirm the stability of the dyad during the catalytic process.", "author": [ { "family": "Kap", "given": " Zeynep" }, { "family": "Karadas", "given": " Ferdi" } ], "container_title": "FARADAY DISCUSSIONS", "id": "72841", "issued": { "date-parts": [ [ 2019, 1, 1 ] ] }, "page": "111-122", "title": "Visible light-driven water oxidation with a ruthenium sensitizer and a cobalt-based catalyst connected with a polymeric platform", "type": "article-journal", "volume": "215" }
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