1 Ocak 2019 Dergi makalesi Açık Erişim

Berkem, Ali Sabri; Capoglu, Ahmet; Nugay, Turgut; Sancaktar, Erol; Anac, Ilke

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  <dc:creator>Berkem, Ali Sabri</dc:creator>
  <dc:creator>Capoglu, Ahmet</dc:creator>
  <dc:creator>Nugay, Turgut</dc:creator>
  <dc:creator>Sancaktar, Erol</dc:creator>
  <dc:creator>Anac, Ilke</dc:creator>
  <dc:date>2019-01-01</dc:date>
  <dc:description>The self-healing ability can be imparted to the polymers by different mechanisms. In this study, self-healing polydimethylsiloxane-graft-polyurethane (PDMS-g-PUR)/Vanadium pentoxide (V2O5) nanofiber supramolecular polymer composites based on a reversible hydrogen bonding mechanism are prepared. V2O5 nanofibers are synthesized via colloidal route and characterized by XRD, SEM, EDX, and TEM techniques. In order to prepare PDMS-g-PUR, linear aliphatic PUR having one -COOH functional group (PUR-COOH) is synthesized and grafted onto aminopropyl functionalized PDMS by EDC/HCl coupling reaction. PUR-COOH and PDMS-g-PUR are characterized by H-1 NMR, FTIR. PDMS-g-PUR/V2O5 nanofiber composites are prepared and characterized by DSC/TGA, FTIR, and tensile tests. The self-healing ability of PDMS-graft-PUR and composites are determined by mechanical tests and optical microscope. Tensile strength data obtained from mechanical tests show that healing efficiencies of PDMS-g-PUR increase with healing time and reach 85.4 +/- 1.2 % after waiting 120 min at 50 degrees C. The addition of V2O5 nanofibers enhances the mechanical properties and healing efficiency of the PDMS-g-PUR. An increase of healing efficiency and max tensile strength from 85.4 +/- 1.2% to 95.3 +/- 0.4% and 113.08 +/- 5.24 kPa to 1443.40 +/- 8.96 kPa is observed after the addition of 10 wt % V2O5 nanofiber into the polymer.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/71263</dc:identifier>
  <dc:identifier>oai:zenodo.org:71263</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>POLYMERS 11(1)</dc:source>
  <dc:title>Self-Healable Supramolecular Vanadium Pentoxide Reinforced Polydimethylsiloxane-Graft-Polyurethane Composites</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
</oai_dc:dc>