1 Ocak 2019 Dergi makalesi Açık Erişim

Berkem, Ali Sabri; Capoglu, Ahmet; Nugay, Turgut; Sancaktar, Erol; Anac, Ilke

DataCite XML

<?xml version='1.0' encoding='utf-8'?>
<resource xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://datacite.org/schema/kernel-4" xsi:schemaLocation="http://datacite.org/schema/kernel-4 http://schema.datacite.org/meta/kernel-4.1/metadata.xsd">
  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/71263</identifier>
  <creators>
    <creator>
      <creatorName>Berkem, Ali Sabri</creatorName>
      <givenName>Ali Sabri</givenName>
      <familyName>Berkem</familyName>
    </creator>
    <creator>
      <creatorName>Capoglu, Ahmet</creatorName>
      <givenName>Ahmet</givenName>
      <familyName>Capoglu</familyName>
      <affiliation>Gebze Tech Unviers, Dept Mat Sci &amp; Engn, TR-41400 Kocaeli, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Nugay, Turgut</creatorName>
      <givenName>Turgut</givenName>
      <familyName>Nugay</familyName>
      <affiliation>Bogazici Univ, Dept Chem, TR-34342 Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Sancaktar, Erol</creatorName>
      <givenName>Erol</givenName>
      <familyName>Sancaktar</familyName>
      <affiliation>Univ Akron, Dept Polymer Engn, Akron, OH 44325 USA</affiliation>
    </creator>
    <creator>
      <creatorName>Anac, Ilke</creatorName>
      <givenName>Ilke</givenName>
      <familyName>Anac</familyName>
      <affiliation>Gebze Tech Unviers, Dept Mat Sci &amp; Engn, TR-41400 Kocaeli, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Self-Healable Supramolecular Vanadium Pentoxide Reinforced Polydimethylsiloxane-Graft-Polyurethane Composites</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2019</publicationYear>
  <dates>
    <date dateType="Issued">2019-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/71263</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.3390/polym11010041</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">The self-healing ability can be imparted to the polymers by different mechanisms. In this study, self-healing polydimethylsiloxane-graft-polyurethane (PDMS-g-PUR)/Vanadium pentoxide (V2O5) nanofiber supramolecular polymer composites based on a reversible hydrogen bonding mechanism are prepared. V2O5 nanofibers are synthesized via colloidal route and characterized by XRD, SEM, EDX, and TEM techniques. In order to prepare PDMS-g-PUR, linear aliphatic PUR having one -COOH functional group (PUR-COOH) is synthesized and grafted onto aminopropyl functionalized PDMS by EDC/HCl coupling reaction. PUR-COOH and PDMS-g-PUR are characterized by H-1 NMR, FTIR. PDMS-g-PUR/V2O5 nanofiber composites are prepared and characterized by DSC/TGA, FTIR, and tensile tests. The self-healing ability of PDMS-graft-PUR and composites are determined by mechanical tests and optical microscope. Tensile strength data obtained from mechanical tests show that healing efficiencies of PDMS-g-PUR increase with healing time and reach 85.4 +/- 1.2 % after waiting 120 min at 50 degrees C. The addition of V2O5 nanofibers enhances the mechanical properties and healing efficiency of the PDMS-g-PUR. An increase of healing efficiency and max tensile strength from 85.4 +/- 1.2% to 95.3 +/- 0.4% and 113.08 +/- 5.24 kPa to 1443.40 +/- 8.96 kPa is observed after the addition of 10 wt % V2O5 nanofiber into the polymer.</description>
  </descriptions>
</resource>