Dergi makalesi Açık Erişim
Najib, Sumaiyah; Bakan, Feray; Abdullayeva, Nazrin; Bahariqushchi, Rahim; Kasap, Sibel; Franzo, Giorgia; Sankir, Mehmet; Sankir, Nurdan Demirci; Mirabella, Salvo; Erdem, Emre
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"affiliation": "Sabanci Univ, Fac Engn & Nat Sci, TR-34956 Istanbul, Turkey",
"name": "Najib, Sumaiyah"
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{
"affiliation": "Sabanci Univ, SUNUM Nanotechnol Res Ctr, TR-34956 Istanbul, Turkey",
"name": "Bakan, Feray"
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{
"affiliation": "TOBB Univ Econ & Technol, Micro & Nanotechnol Grad Program, Sogutozu Cad 43 Sogutozu, TR-06560 Ankara, Turkey",
"name": "Abdullayeva, Nazrin"
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{
"affiliation": "IMM CNR, Via S Sofia 64, I-95123 Catania, Italy",
"name": "Bahariqushchi, Rahim"
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{
"affiliation": "Sabanci Univ, SUNUM Nanotechnol Res Ctr, TR-34956 Istanbul, Turkey",
"name": "Kasap, Sibel"
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{
"affiliation": "IMM CNR, Via S Sofia 64, I-95123 Catania, Italy",
"name": "Franzo, Giorgia"
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"description": "Zinc oxide (ZnO) nanostructures were synthesized in the form of nanoparticles, nanoflowers and nanourchins. Structural, electronic and optical characterization of the samples was performedviastandard techniques such as X-ray diffraction (XRD), scanning electron microscopy (SEM), photoluminescence, Raman and ultraviolet-visible (UV-Vis) spectroscopy. Point defect structures which are specific to each morphology have been investigated in terms of their concentration and locationviastate-of-the-art electron paramagnetic resonance (EPR) spectroscopy. According to the core-shell model, all the samples revealed core defects; however, the defects on the surface are smeared out. Finally, all three morphologies have been tested as electrode materials in a real supercapacitor device and the performance of the device, in particular, the specific capacitance and the storage mechanism, has been mediated by the point defects. Morphology-dependent defective ZnO electrodes enable the monitoring of the working principle of the supercapacitor device ranging from electric double-layer capacitors (EDLC) to pseudo-supercapacitors.",
"doi": "10.1039/d0nr03921g",
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"issue": "30",
"pages": "16162-16172",
"title": "NANOSCALE",
"volume": "12"
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"title": "Tailoring morphology to control defect structures in ZnO electrodes for high-performance supercapacitor devices"
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