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Tailoring morphology to control defect structures in ZnO electrodes for high-performance supercapacitor devices

Najib, Sumaiyah; Bakan, Feray; Abdullayeva, Nazrin; Bahariqushchi, Rahim; Kasap, Sibel; Franzo, Giorgia; Sankir, Mehmet; Sankir, Nurdan Demirci; Mirabella, Salvo; Erdem, Emre


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/7011</identifier>
  <creators>
    <creator>
      <creatorName>Najib, Sumaiyah</creatorName>
      <givenName>Sumaiyah</givenName>
      <familyName>Najib</familyName>
      <affiliation>Sabanci Univ, Fac Engn &amp; Nat Sci, TR-34956 Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Bakan, Feray</creatorName>
      <givenName>Feray</givenName>
      <familyName>Bakan</familyName>
      <affiliation>Sabanci Univ, SUNUM Nanotechnol Res Ctr, TR-34956 Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Abdullayeva, Nazrin</creatorName>
      <givenName>Nazrin</givenName>
      <familyName>Abdullayeva</familyName>
      <affiliation>TOBB Univ Econ &amp; Technol, Micro &amp; Nanotechnol Grad Program, Sogutozu Cad 43 Sogutozu, TR-06560 Ankara, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Bahariqushchi, Rahim</creatorName>
      <givenName>Rahim</givenName>
      <familyName>Bahariqushchi</familyName>
      <affiliation>IMM CNR, Via S Sofia 64, I-95123 Catania, Italy</affiliation>
    </creator>
    <creator>
      <creatorName>Kasap, Sibel</creatorName>
      <givenName>Sibel</givenName>
      <familyName>Kasap</familyName>
      <affiliation>Sabanci Univ, SUNUM Nanotechnol Res Ctr, TR-34956 Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Franzo, Giorgia</creatorName>
      <givenName>Giorgia</givenName>
      <familyName>Franzo</familyName>
      <affiliation>IMM CNR, Via S Sofia 64, I-95123 Catania, Italy</affiliation>
    </creator>
    <creator>
      <creatorName>Sankir, Mehmet</creatorName>
      <givenName>Mehmet</givenName>
      <familyName>Sankir</familyName>
    </creator>
    <creator>
      <creatorName>Sankir, Nurdan Demirci</creatorName>
      <givenName>Nurdan Demirci</givenName>
      <familyName>Sankir</familyName>
    </creator>
    <creator>
      <creatorName>Mirabella, Salvo</creatorName>
      <givenName>Salvo</givenName>
      <familyName>Mirabella</familyName>
    </creator>
    <creator>
      <creatorName>Erdem, Emre</creatorName>
      <givenName>Emre</givenName>
      <familyName>Erdem</familyName>
    </creator>
  </creators>
  <titles>
    <title>Tailoring Morphology To Control Defect Structures In Zno Electrodes For High-Performance Supercapacitor Devices</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2020</publicationYear>
  <dates>
    <date dateType="Issued">2020-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/7011</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1039/d0nr03921g</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">Zinc oxide (ZnO) nanostructures were synthesized in the form of nanoparticles, nanoflowers and nanourchins. Structural, electronic and optical characterization of the samples was performedviastandard techniques such as X-ray diffraction (XRD), scanning electron microscopy (SEM), photoluminescence, Raman and ultraviolet-visible (UV-Vis) spectroscopy. Point defect structures which are specific to each morphology have been investigated in terms of their concentration and locationviastate-of-the-art electron paramagnetic resonance (EPR) spectroscopy. According to the core-shell model, all the samples revealed core defects; however, the defects on the surface are smeared out. Finally, all three morphologies have been tested as electrode materials in a real supercapacitor device and the performance of the device, in particular, the specific capacitance and the storage mechanism, has been mediated by the point defects. Morphology-dependent defective ZnO electrodes enable the monitoring of the working principle of the supercapacitor device ranging from electric double-layer capacitors (EDLC) to pseudo-supercapacitors.</description>
  </descriptions>
</resource>
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