1 Ocak 2019 Dergi makalesi Açık Erişim

Sarioglu, Ahmet Oral; Sonmez, Mehmet; Yalcin, Serife Pinar; Ceylan, Umit; Aygun, Muhittin

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        "affiliation": "Gaziantep Univ, Fac Arts & Sci, Dept Chem, Gaziantep, Turkey", 
        "name": "Sarioglu, Ahmet Oral"
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      {
        "affiliation": "Gaziantep Univ, Fac Arts & Sci, Dept Chem, Gaziantep, Turkey", 
        "name": "Sonmez, Mehmet"
      }, 
      {
        "affiliation": "Harran Univ, Fac Arts & Sci, Dept Phys, Sanliurfa, Turkey", 
        "name": "Yalcin, Serife Pinar"
      }, 
      {
        "affiliation": "Giresun Univ, Vocat High Sch Hlth Serv, Dept Med Serv & Tech, Giresun, Turkey", 
        "name": "Ceylan, Umit"
      }, 
      {
        "affiliation": "Dokuz Eylul Univ, Fac Arts & Sci, Dept Phys, Izmir, Turkey", 
        "name": "Aygun, Muhittin"
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    "description": "-Diketone lanthanide complexes are used mainly in lighting, telecommunication, screens, safety inks, and marking as well as in the field of luminescent materials for probes in biosciences. Two new lanthanide ternary complexes, the general formula Eu(BCPP)(3)(Phen) and Tb(BCPP)(3)(Phen), combined 1,3-bis(4-chlorophenyl)-1,3-propanedione (BCPP) with 1,10-phenanthroline as a secondary ligand, were synthesized and structurally characterized by single crystal X-ray diffraction, elemental analysis, FT-IR, and MALDI-TOF MS. Single crystal X-ray diffraction analysis revealed that these Eu(III) and Tb(III) complexes displayed bidentate ligands and a square antiprism geometry for the metal center. Also, the absorption and thermal behavior of these lanthanide complexes were investigated. When the maximum absorption of the lanthanide complexes was compared, it was observed that the absorption wavelength of the lanthanide complexes were red shifted in DMSO, DMF, and DCM, depending on the polarity of the solvent.", 
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    "journal": {
      "issue": "5-7", 
      "pages": "1108-1118", 
      "title": "JOURNAL OF COORDINATION CHEMISTRY", 
      "volume": "72"
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    "publication_date": "2019-01-01", 
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    "title": "Eu(III) and Tb(III) complexes of 1,3-bis(4-chlorophenyl)-1,3-propanedione combined with phenanthroline ligand: synthesis, structural characterization, and thermogravimetric studies"
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