1 Ocak 2019 Dergi makalesi Açık Erişim

Sarioglu, Ahmet Oral; Sonmez, Mehmet; Yalcin, Serife Pinar; Ceylan, Umit; Aygun, Muhittin

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/68395</identifier>
  <creators>
    <creator>
      <creatorName>Sarioglu, Ahmet Oral</creatorName>
      <givenName>Ahmet Oral</givenName>
      <familyName>Sarioglu</familyName>
      <affiliation>Gaziantep Univ, Fac Arts &amp; Sci, Dept Chem, Gaziantep, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Sonmez, Mehmet</creatorName>
      <givenName>Mehmet</givenName>
      <familyName>Sonmez</familyName>
      <affiliation>Gaziantep Univ, Fac Arts &amp; Sci, Dept Chem, Gaziantep, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Yalcin, Serife Pinar</creatorName>
      <givenName>Serife Pinar</givenName>
      <familyName>Yalcin</familyName>
      <affiliation>Harran Univ, Fac Arts &amp; Sci, Dept Phys, Sanliurfa, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Ceylan, Umit</creatorName>
      <givenName>Umit</givenName>
      <familyName>Ceylan</familyName>
      <affiliation>Giresun Univ, Vocat High Sch Hlth Serv, Dept Med Serv &amp; Tech, Giresun, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Aygun, Muhittin</creatorName>
      <givenName>Muhittin</givenName>
      <familyName>Aygun</familyName>
      <affiliation>Dokuz Eylul Univ, Fac Arts &amp; Sci, Dept Phys, Izmir, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Eu(Iii) And Tb(Iii) Complexes Of 1,3-Bis(4-Chlorophenyl)-1,3-Propanedione Combined With Phenanthroline Ligand: Synthesis, Structural Characterization, And Thermogravimetric Studies</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2019</publicationYear>
  <dates>
    <date dateType="Issued">2019-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/68395</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1080/00958972.2019.1593387</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">-Diketone lanthanide complexes are used mainly in lighting, telecommunication, screens, safety inks, and marking as well as in the field of luminescent materials for probes in biosciences. Two new lanthanide ternary complexes, the general formula Eu(BCPP)(3)(Phen) and Tb(BCPP)(3)(Phen), combined 1,3-bis(4-chlorophenyl)-1,3-propanedione (BCPP) with 1,10-phenanthroline as a secondary ligand, were synthesized and structurally characterized by single crystal X-ray diffraction, elemental analysis, FT-IR, and MALDI-TOF MS. Single crystal X-ray diffraction analysis revealed that these Eu(III) and Tb(III) complexes displayed bidentate ligands and a square antiprism geometry for the metal center. Also, the absorption and thermal behavior of these lanthanide complexes were investigated. When the maximum absorption of the lanthanide complexes was compared, it was observed that the absorption wavelength of the lanthanide complexes were red shifted in DMSO, DMF, and DCM, depending on the polarity of the solvent.</description>
  </descriptions>
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