1 Ocak 2016 Dergi makalesi Açık Erişim

Karatepe, Ozlem; Yildiz, Yunus; Pamuk, Handan; Eris, Sinan; Dasdelen, Zeynep; Sen, Fatih

Dublin Core

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  <dc:creator>Karatepe, Ozlem</dc:creator>
  <dc:creator>Yildiz, Yunus</dc:creator>
  <dc:creator>Pamuk, Handan</dc:creator>
  <dc:creator>Eris, Sinan</dc:creator>
  <dc:creator>Dasdelen, Zeynep</dc:creator>
  <dc:creator>Sen, Fatih</dc:creator>
  <dc:date>2016-01-01</dc:date>
  <dc:description>Highly monodisperse Pt nanocomposites (Pt@ PPy-PANI NPs) supported on polypyrrole (PPy)-polyaniline (PANI) have been successfully synthesized for the first time by a simple one-pot process, which involves the simultaneous reduction of the conducting polypyrrole (PPy)-polyaniline (PANI) and Pt precursors using DMAB (dimethylamine borane) as a reductant under ultrasonic conditions. Pt@ PPy-PANI NPs have been characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). All the results show that highly crystalline and stable colloidal Pt@ PPy-PANI NPs have been formed as one of the most active and long-lived catalysts with superior reusability performance for the electro-oxidation of methanol at room temperature. Compared to PPy or PANI supported Pt nanoparticles, Pt@ PPy-PANI NPs exhibit extraordinary electrocatalytic activity and stability toward the electro-oxidation of methanol, showing their potential use as a new electrode material for direct methanol fuel cells (DMFCs). It should be primarily attributed to the PPy-PANI, which not only provided larger surface area and flaws for the deposition of Pt nanoparticles, but also the adsorption of more methanol molecules for further oxidation.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/59161</dc:identifier>
  <dc:identifier>oai:zenodo.org:59161</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>RSC ADVANCES 6(56) 50851-50857</dc:source>
  <dc:title>Enhanced electrocatalytic activity and durability of highly monodisperse Pt@PPy-PANI nanocomposites as a novel catalyst for the electro-oxidation of methanol</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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