1 Ocak 2016 Dergi makalesi Açık Erişim

Karatepe, Ozlem; Yildiz, Yunus; Pamuk, Handan; Eris, Sinan; Dasdelen, Zeynep; Sen, Fatih

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        "affiliation": "Dumlupinar Univ, Sen Res Grp, Dept Biochem, Fac Arts & Sci, EvliyaCelebi Campus, TR-43100 Kutahya, Turkey", 
        "name": "Karatepe, Ozlem"
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      {
        "affiliation": "Dumlupinar Univ, Sen Res Grp, Dept Biochem, Fac Arts & Sci, EvliyaCelebi Campus, TR-43100 Kutahya, Turkey", 
        "name": "Yildiz, Yunus"
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      {
        "affiliation": "Dumlupinar Univ, Sen Res Grp, Dept Biochem, Fac Arts & Sci, EvliyaCelebi Campus, TR-43100 Kutahya, Turkey", 
        "name": "Pamuk, Handan"
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      {
        "affiliation": "Dumlupinar Univ, Sen Res Grp, Dept Biochem, Fac Arts & Sci, EvliyaCelebi Campus, TR-43100 Kutahya, Turkey", 
        "name": "Eris, Sinan"
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      {
        "affiliation": "Dumlupinar Univ, Sen Res Grp, Dept Biochem, Fac Arts & Sci, EvliyaCelebi Campus, TR-43100 Kutahya, Turkey", 
        "name": "Dasdelen, Zeynep"
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      {
        "affiliation": "Dumlupinar Univ, Sen Res Grp, Dept Biochem, Fac Arts & Sci, EvliyaCelebi Campus, TR-43100 Kutahya, Turkey", 
        "name": "Sen, Fatih"
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    "description": "Highly monodisperse Pt nanocomposites (Pt@ PPy-PANI NPs) supported on polypyrrole (PPy)-polyaniline (PANI) have been successfully synthesized for the first time by a simple one-pot process, which involves the simultaneous reduction of the conducting polypyrrole (PPy)-polyaniline (PANI) and Pt precursors using DMAB (dimethylamine borane) as a reductant under ultrasonic conditions. Pt@ PPy-PANI NPs have been characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). All the results show that highly crystalline and stable colloidal Pt@ PPy-PANI NPs have been formed as one of the most active and long-lived catalysts with superior reusability performance for the electro-oxidation of methanol at room temperature. Compared to PPy or PANI supported Pt nanoparticles, Pt@ PPy-PANI NPs exhibit extraordinary electrocatalytic activity and stability toward the electro-oxidation of methanol, showing their potential use as a new electrode material for direct methanol fuel cells (DMFCs). It should be primarily attributed to the PPy-PANI, which not only provided larger surface area and flaws for the deposition of Pt nanoparticles, but also the adsorption of more methanol molecules for further oxidation.", 
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      "issue": "56", 
      "pages": "50851-50857", 
      "title": "RSC ADVANCES", 
      "volume": "6"
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      "title": "Dergi makalesi", 
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    "title": "Enhanced electrocatalytic activity and durability of highly monodisperse Pt@PPy-PANI nanocomposites as a novel catalyst for the electro-oxidation of methanol"
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