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Syntheses and structural characterization of new trans-bis-[n-butyl-(p-methoxyphenyl) dithiophosphinato] nickel(II), the pyridine derivative thereof, and bis-{bis-[n-butyl-(p-methoxyphenyl) dithiophosphinato]cobalt(II)} complexes

Saglam, Ertugrul Gazi; Dal, Hakan; Mougang-Soume, Berline; Hokelek, Tuncer


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        "affiliation": "Bozok Univ, Dept Chem, TR-66900 Yozgat, Turkey", 
        "name": "Saglam, Ertugrul Gazi"
      }, 
      {
        "affiliation": "Anadolu Univ, Open Educ Fac, Dept Med Serv & Tech, TR-26470 Tepebasi, Eskisehir, Turkey", 
        "name": "Dal, Hakan"
      }, 
      {
        "affiliation": "Univ Montreal, Dept Chem, Montreal, PQ, Canada", 
        "name": "Mougang-Soume, Berline"
      }, 
      {
        "affiliation": "Hacettepe Univ, Dept Phys, TR-06800 Ankara, Turkey", 
        "name": "Hokelek, Tuncer"
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    "description": "Three new metal complexes of ammonium n-butyl-(p-methoxyphenyl) dithiophosphinate (NH4L) were synthesized. NH4L was treated with NiCl2 center dot 6H(2)O and CoCl2 center dot 6H(2)O in ethanol to obtain a new trans-bis-[n-butyl-(p-methoxyphenyl) dithiophosphinato]nickel(II) and bis-{bis-[n-butyl-(p-methoxyphenyl) dithiophosphinato]cobalt(II)} complexes, ([Ni(L)(2)] and [Co-2(mu-L)(2)(L)(2)], respectively). Square-planar nickel(II) complex was furthermore reacted with excess pyridine (Py) and the octahedral {bis-pyridine-bis-[n-butyl-(p-methoxyphenyl)]}nikel(II) complex, ([Ni(L)(2)(Py)(2)]), was obtained.", 
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    "title": "Syntheses and structural characterization of new trans-bis-[n-butyl-(p-methoxyphenyl) dithiophosphinato] nickel(II), the pyridine derivative thereof, and bis-{bis-[n-butyl-(p-methoxyphenyl) dithiophosphinato]cobalt(II)} complexes"
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